In this work, the thermal sensing capability of Nd 3+ -doped Y 3 Al 5 O 12 nanoparticles fabricated by combustion synthesis is reported. Under excitation at 808 nm, the relative intensity of the two spectrally isolated luminescence peaks located at around 940 nm (corresponding to a 4 F 3/2 → 4 I 9/2 transition of the Nd 3+ ions) is found to be markedly temperature-dependent allowing for ratiometric luminescence nanothermometry. The potential use of neodymium-doped yttrium aluminum garnet nanoparticles in nanothermometry has been successfully tested in a variety of systems including integrated microelectronics, optofl uidic devices, and subtissue ex vivo experiments.
A yellow-emitting phosphor, La1−xCex3+Sr2AlO5, is reported that displays a peak in the excitation at 450nm and a peak in the emission at 556nm. When this phosphor is pumped by a blue InGaN light-emitting diode (λmax=450nm) we obtain white light with color rendering index (Ra) between 81 and 85 and color temperatures between 4200 and 5500K, suggesting that this material is competitive as a blue-pumped yellow phosphors.
The spectroscopic properties of different infrared-emitting neodymium-doped nanoparticles (LaF 3 :Nd 3þ , SrF 2 :Nd 3þ , NaGdF 4 : Nd 3þ , NaYF 4 : Nd 3þ , KYF 4 : Nd 3þ , GdVO 4 : Nd 3þ , and Nd:YAG) have been systematically analyzed. A comparison of the spectral shapes of both emission and absorption spectra is presented, from which the relevant role played by the host matrix is evidenced. The lack of a "universal" optimum system for infrared bioimaging is discussed, as the specific bioimaging application and the experimental setup for infrared imaging determine the neodymiumdoped nanoparticle to be preferentially used in each case. V C 2015 AIP Publishing LLC.
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