Gas flow behavior in porous media with micro- and nanoscale pores has always been attracted great attention. Gas transport mechanism in such pores is a complex problem, which includes continuous flow, slip flow and transition flow. In this study, the microtubes of quartz microcapillary and nanopores alumina membrane were used, and the gas flow measurements through the microtubes and nanopores with the diameters ranging from 6.42 μm to 12.5 nm were conducted. The experimental results show that the gas flow characteristics are in rough agreement with the Hagen-Poiseuille (H-P) equation in microscale. However, the flux of gas flow through the nanopores is larger than the H-P equation by more than an order of magnitude, and thus the H-P equation considerably underestimates gas flux. The Knudsen diffusion and slip flow coexist in the nanoscale pores and their contributions to the gas flux increase as the diameter decreases. The slip flow increases with the decrease in diameter, and the slip length decreases with the increase in driving pressure. Furthermore, the experimental gas flow resistance is less than the theoretical value in the nanopores and the flow resistance decreases along with the decrease in diameter, which explains the phenomenon of flux increase and the occurrence of a considerable slip length in nanoscale. These results can provide insights into a better understanding of gas flow in micro- and nanoscale pores and enable us to exactly predict and actively control gas slip.

The low-permeability reservoirs are of heavy heterogeneity, low permeability, fine oil-water passages, strong resistance during flow, and the significant interaction between solid and liquid interfaces causes the flow of fluid in reservoir deviating from the Darcy's law. There is no agreement on the interaction between the various factors in seepage process and the influence of seepage law. The boundary layer exists when liquid flow in micro-tubes and nano-tubes, and the boundary layer decreases with the increase of driving force, and the maximum value of boundary layer ratio is equal to 1. Based on the capillary boundal model and the boundary layer theory, a new exponential seepage model for low permeability reservoirs was proposed. Some experiments of water flow with different pressure gradient were carried out in low permeability cores with permeability of 4 to 8 milidarcy in natural rock cores from an oilfield in China, and the nonlinear model is of good agreement with the single-phase water flooding experiments of these cores. The results demonstrate that the physical meaning of each parameter of the new model is clear and it can be applied to describe the nonlinear characteristics of low permeability reservoirs. The large driving force can overcome disadvantages in the developments of low permeability reservoirs.

Nanotechnology provides potential benefits for enhanced oil recovery (EOR) in low-permeability reservoirs. In this paper, SiO2/P­(MBAAm-co-AM) composite nanoparticles were prepared using the distillation precipitation polymerization method. Scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis were employed to characterize the morphology and microstructure of nanoparticles. The swelling behavior of polymeric nanoparticles in brine was investigated to evaluate the effect of salinity and temperature. Kinetic and thermodynamic analyses were employed to reveal the swelling mechanism. Displacement experiments were performed to investigate their performance in EOR in low-permeability reservoirs. The results show that the swelling ratio of SiO2/P­(MBAAm-co-AM) composite nanoparticles is higher at low salinity and high temperature, which can be explained by the Flory theory. The swelling process is spontaneous and endothermic, being controlled by physical adsorption involving the diffusion of water molecules, which complies with the first-order kinetics model. The suspension of SiO2/P­(MBAAm-co-AM) composite nanoparticles can improve incremental oil recovery from 10.28 to 21.97% with an increase of the swelled particle size from 580 to 1160 nm. It is feasible that core–shell polymeric nanoparticles can be used for EOR in low-permeability reservoirs.

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