In recent years, metal–organic frameworks (MOFs) have been extensively investigated for diverse heterogeneous catalysis due to their diversity of structures and outstanding physical and chemical properties. Currently, most related work focuses on employing MOFs as porous substrate materials to fabricate confined nanoparticle or heteroatom-doped electrocatalysts which have to be annealed at high temperature before application. However, the annealing process would destroy the structure completely and lose the intrinsic active sites in MOFs framework. Herein, a simple solvothermal process is used to synthesize a series of Fe/Ni bimetallic MOFs. The as-prepared MOFs are applied directly as highly efficient oxygen evolution reaction (OER) electrocatalysts with no post-annealing treatment. The bimetallic FeNi-MOFs show higher OER activity than single metal MOFs and commercial precious RuO2 catalysts. With the optimized FeNi-MOF as the catalyst, the OER current densities of 50 and 100 mA/cm2 can be achieved at the overpotentials of only 270 and 287 mV, respectively. Meanwhile, a small Tafel slope of 49 mV/dec was obtained. Moreover, this catalyst shows high electrochemical stability in strong basic solution. This work demonstrates that through structural optimization, bimetallic and multimetallic MOFs may have promising potentials as advanced catalysts for electrochemical energy conversion.
Water oxidation is a critical process for electrochemical water splitting due to its inherent sluggish kinetics. In spite of the high catalytic activities of noble metal-based electrocatalysts for water oxidation, their high cost, rare reserves, and low stabilities drive researchers to exploit efficient but lowcost electrocatalysts. Ultrathin 2D nanomaterials are considered efficient electrocatalysts for oxygen evolution reaction (OER) in water splitting. Herein, a facile strategy is proposed to fabricate 2D FeNi layered double hydroxide (FeNi-LDH) nanosheets packed with the in situ produced 1D sword-like FeNi-MOFs by using FeNi-LDH as a semi-sacrificial template. In the composite, the thickness of the formed nanosheets is only 1.34 nm, much thinner than that of most previously reported 2D materials. The 1D porous sword-like MOF nanorods have a long length of around 1.3 µm. Due to the unique 2D/1D combined structure, the as-prepared FeNi LDH/MOF is directly used as electrocatalyst for the OER displays enhanced OER electrocatalytic performance with a low overpotential of 272 mV@100 mA cm -2 , a small Tafel slope of 34.1 mV dec -1 , high long-term durability. This work provides a new way to fabricate integrated ultrathin 2D nanosheets and MOFs as advanced catalysts for electrochemical energy conversion.
Energy-efficient, low-cost, and highly durable catalysts for the electrochemical hydrogen evolution reaction (HER) and urea oxidation reaction (UOR) are extremely important for related sustainable energy systems. In the present work, hierarchical coassembled cobalt molybdenum sulfide nanosheets deposited on carbon cloth (CC) were synthesized as catalysts for hydrogen evolution and urea oxidation. By adjusting the doping amount of Mo, 2D nanosheets with different morphologies and compositions (Co x Mo y S-CC) can be obtained. The as-prepared nanosheet materials with abundant active sites exhibit superior properties on the electrochemical HER and UOR in alkaline medium. Significantly, the Mo-doping concentration and composition of the formed nanosheets have large effects on the electrocatalytic activity. The fabricated nanosheets with optimal Mo doping (Co3Mo1S-CC) illustrate the best catalytic properties for the HER in N2-saturated 1.0 M KOH. A small overpotential (85 mV) is needed to meet the current density of 10 mA/cm2. This study indicates that the doping of an appropriate amount of molybdenum into CoS2 nanosheets can efficiently improve the catalytic performance. Also, the nanosheet catalyst exhibits an extremely high electrocatalytic activity for the UOR, and the electrochemical results indicate that a relatively low cell voltage of 1.50 V is needed to obtain the current density of 10 mA/cm2. The present work demonstrates the potential application of CoMoS nanosheets in the energy electrocatalysis area and the insights into performance-boosting through heteroatom doping and optimization of the composition and structure.
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