The launch of the big data era puts forward challenges for information preservation technology, both in storage capacity and security. Herein, a brand new optical storage medium, transparent glass ceramic (TGC) embedded with photostimulated LiGa 5 O 8 : Mn 2+ nanocrystals, capable of achieving bit-by-bit optical data write-in and read-out in a photon trapping/detrapping mode, is developed. The highly ordered nanostructure enables light-matter interaction with high encoding/decoding resolution and low bit error rate. Importantly, going beyond traditional 2D optical storage, the high transparency of the studied bulk medium makes 3D volumetric optical data storage (ODS) possible, which brings about the merits of expanded storage capacity and improved information security. Demonstration application confirmed the erasable-rewritable 3D storage of binary data and display items in TGC with intensity/ wavelength multiplexing. The present work highlights a great leap in photostimulated material for ODS application and hopefully stimulates the development of new multi-dimensional ODS media.
Rare earth (RE3+)-doped phosphors generally suffer from thermal quenching, in which their photoluminescence (PL) intensities decrease at high temperatures. Herein, we report a class of unique two-dimensional negative-thermal-expansion phosphor of Sc2(MoO4)3:Yb/Er. By virtue of the reduced distances between sensitizers and emitters as well as confined energy migration with increasing the temperature, a 45-fold enhancement of green upconversion (UC) luminescence and a 450-fold enhancement of near-infrared downshifting (DS) luminescence of Er3+ are achieved upon raising the temperature from 298 to 773 K. The thermally boosted UC and DS luminescence mechanism is systematically investigated through in situ temperature-dependent Raman spectroscopy, synchrotron X-ray diffraction and PL dynamics. Moreover, the luminescence lifetime of 4I13/2 of Er3+ in Sc2(MoO4)3:Yb/Er displays a strong temperature dependence, enabling luminescence thermometry with the highest relative sensitivity of 12.3%/K at 298 K and low temperature uncertainty of 0.11 K at 623 K. These findings may gain a vital insight into the design of negative-thermal-expansion RE3+-doped phosphors for versatile applications.
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