several misprints remained in the text. The correct text reads as follows:Page 954, Column 2, Equations (4) and (6) For the reader's convenience, we take this opportunity to correct Equations (4) to (6):where R (m) is the radius of the consumed iron particle and h the coefficient of volumetric expansion. The proportion of consumed iron (% consumed Fe) is given by:It is possible to determine the proportion of consumed iron when the volume of the iron corrosion product without the volume of the consumed Fe (V Fe3O4 -V consumed Fe ) is equal to the initial porosity F 0 (m 3 ) according to:
The equilibrium sorption of a local Ayous (Triplochiton scleroxylon) wood sawdust was examined as substitute adsorbent for removal of paraquat from water. Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (DRK) isotherms were used to compare the equilibrium sorption data obtained. The separation factor revealed a constructive sorption experiment since the maximum monolayer coverage (Q 0 ) from Langmuir isotherm model was found out to be 41.66 µmol/g. In addition, the correlation value of Langmuir isotherm model was the maximum among the four adsorption isotherms. From Freundlich isotherm model, the sorption intensity (n) that denotes favorable sorption and the correlation value are 2.402 and 0.929, respectively. Temkin isotherm model was used to calculate the heat of sorption process which corresponds to 18.39 J/mol, and the mean free energy was estimated from DRK isotherm model to be 0.091 kJ/mol which vividly proved that the adsorption experiment was obeyed to a physical process. The results indicate that this local wood sawdust could be employed as an economical material for reducing paraquat from industrial wastewater.
several misprints remained in the text. The correct text reads as follows: Page 954, Column 2, Equations (4) and (6) For the reader's convenience, we take this opportunity to correct Equations (4) to (6): V Fe3O4 À V consumed Fe ¼ N h À 1 ð Þ 4 3 p R 3 0 À R 3 À Á (4) where R (m) is the radius of the consumed iron particle and h the coefficient of volumetric expansion. The proportion of consumed iron (% consumed Fe) is given by: % consumed Fe ¼ 100 R 3 0 ÀR 3 R 3 0 (5) It is possible to determine the proportion of consumed iron when the volume of the iron corrosion product without the volume of the consumed Fe (V Fe3O4-V consumed Fe) is equal to the initial porosity F 0 (m 3) according to: % consumed Fe V Fe3O4 À V consumed Fe ¼ F0 ð Þ ¼ 100 F 0 N hÀ1 ð Þ 4 3 p R 3 0 (6)
Water pollution is increasingly becoming an issue of global concern, especially in developing countries. Therefore, the development of affordable, reliable, low-maintenance, electricity-free technologies for reducing biological and chemical pollutants in drinking water to an acceptable level for human consumption is an interesting topic of research. The suitability of metallic iron (Fe0) as a universal filter material has been recently discussed. Iron/sand filters have a great potential for rural regions where source water may be subjected to various microbial and chemical contaminations. This is based on the fact that corroding iron has the ability to remove all soluble species by an unspecific mechanism. This article develops a mathematical model of iron(Fe0)/sand filter taking into account the loss of porosity during the filtration process. The porosity loss with time is calculated using the rate of formation of corrosion products. The time after which the porosity is reduced to zero indicating a zero flow rate is estimated. The mass transport advection-dispersion equation is derived to predict, through numerical simulation, the spatiotemporal distribution of pollutants and the flow rate in the filter as well as the water quality at the exit of the filter. The control parameters are the iron proportion, the volume of sand particles, the height of the filter and the sorption coefficient. It is found that the pollutant removal percentage and the service life of the filter depend on the relative proportions of sand and iron in the filter.For instance, taking the guideline equal to be 25% of the influent concentration, simulation results demonstrated that by mixing sand and iron particles in proportion of 40 vol% Fe0, the filter can be used continuously for 83 months.La pollution des eaux devient de plus en plus un problème d’intérêt mondial, particulièrement dans les pays en voie de développement. Par conséquent, le développement de technologies à faible coût et faciles à maintenir, pour réduire les polluants dans les sources d’eau à boire à un niveau acceptable pour la consommation, est un sujet de recherche intéressant. Cet article développe un modèle mathématique de filtre à base de particules de fer (Fe0) et de sable en tenant compte de la perte de porosité au cours du processus de traitement de l’eau. La réduction de la porosité au cours du temps est calculée en tenant compte de la vitesse de formation des produits de corrosion. Le temps après lequel la porosité est réduite à zéro, impliquant un débit d’eau nul à travers le filtre, est calculé. L’équation d’advection-dispersion est établie pour prédire, par simulation numérique, la répartition spatiotemporelle des polluants et le débit d’eau à travers le filtre ainsi que la qualité de l’eau à la sortie du filtre. Les paramètres de contrôle sont ...
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