Uniaxial tensile tests are performed on a polymethyl methacrylate (PMMA) grade over a range of temperatures near the glass transition and over two decades of strain rate.Deformation maps are constructed for Young's modulus, flow strength, and failure strain as a function of temperature for selected strain rates. The glassy, glass transition and rubbery regimes are identified, and constitutive relations are calibrated for the modulus, flow strength and failure strain within each regime.
Bimodal cellular poly(methyl methacrylate) with micro‐ and nano‐sized (300–500 nm) cells with up to 5 wt% of sepiolite nanoparticles and porosity from 50% to 75% are produced by solid‐state foaming. Uniaxial compression tests are performed to measure the effect of sepiolite concentration on the elastic modulus and the yield strength of the solid and cellular nanocomposites. Single edge notch bend tests are conducted to relate the fracture toughness of the solid and cellular nanocomposites to sepiolite concentration. The relative modulus is independent of sepiolite content to within material scatter when considering the complete porosity range. In contrast, a mild enhancement of the relative modulus is observed by the addition of sepiolite particles for the foamed nanocomposites with a porosity close to 50%. The relative compressive strength of the cellular nanocomposites mildly decreases as a function of sepiolite concentration. A strong enhancement of the relative fracture toughness by the addition of sepiolites is observed. The enhancement of the relative fracture toughness and the relative modulus (at 50% porosity) can be attributed to an improved dispersion of the particles due to foaming and the migration of micro‐sized aggregates from the solid phase to the microcellular pores during foaming.
The mechanical response of cellular PMMA of cell size below 50 nm has been measured. • Reducing the cell size from the micro to the nanoscale does not affect the Young's modulus. • Reducing the cell size from the micro to the nanoscale does not affect the yield strength. • The fracture toughness (for a given density) increases when the cell size transitions from the micrometric to the nanometric range.
Solid-state nanofoaming experiments are conducted on two polymethyl methacrylate (PMMA) grades of markedly different molecular weight using CO2 as the blowing agent. The sensitivity of porosity to foaming time and foaming temperature is measured. Also, the microstructure of the PMMA nanofoams is characterized in terms of cell size and cell nucleation density. A one-dimensional numerical model is developed to predict the growth of spherical, gas-filled voids during the solid-state foaming process. Diffusion of CO2 within the PMMA matrix is sufficiently rapid for the concentration of CO2 to remain almost uniform spatially. The foaming model makes use of experimentally calibrated constitutive laws for the uniaxial stress versus strain response of the PMMA grades as a function of strain rate and temperature, and the effect of dissolved CO2 is accounted for by a shift in the glass transition temperature of the PMMA. The maximum achievable porosity is interpreted in terms of cell wall tearing and comparisons are made between the predictions of the model and nanofoaming measurements; it is deduced that the failure strain of the cell walls is sensitive to cell wall thickness.
The tensile strength of an adhesive joint is predicted for a centre-cracked elastic layer, sandwiched between elastic substrates, and subjected to remote tensile stress. A tensile cohesive plastic zone, of Dugdale type, is placed at each crack tip, and the cohesive zone is characterised by a finite strength and a finite toughness. An analytical theory of the fracture strength is developed (and validated by finite element simulations). The macroscopic strength of the adhesive joint is determined as a function of the relative magnitude of crack length, layer thickness, plastic zone size, specimen width and elastic modulus mismatch between layer and substrates. Fracture maps are constructed to reveal competing regimes of behaviour. The maps span the full range of behaviour from a perfectly brittle response (with no crack tip plasticity) to full plastic collapse. When the sum of crack length and cohesive zone length is less than 0.3 times the layer height, the effect of elastic mismatch between substrate and adhesive layer has only a minor influence upon the macroscopic fracture strength. For this case, the cracked adhesive layer behaves as a centre-crack in an infinite solid made from adhesive, and a transition from toughness control to strength control occurs when the crack length is comparable to that of the cohesive zone length. Alternatively, when the sum of crack length and cohesive zone length exceeds 0.3 times the layer height, the elastic mismatch plays a major role; again there is a transition from toughness control to strength control, but it occurs at a ratio of crack length to layer thickness that depends upon both the elastic mismatch and the ratio of cohesive zone length to layer height. The study also highlights the importance of a structural length scale in the form of layer height times modulus mismatch: this scale is on the order of 1 metre when the layer height equals one millimetre and the elastic modulus of the 2 substrate is one thousand times that of the adhesive layer. The in-plane structural dimensions (including crack length) must exceed this structural dimension in order for a remote K-field to exist within the substrate. Experimental validation of the cohesive zone approach is achieved by measuring the sensitivity of fracture strength to crack length and layer height for a centrecracked strip made from cellulose acetate layer, sandwiched between aluminium alloy substrates.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.