A simple determination of the Ag 2 O solubility product, K sp , suitable for introductory, analytical, or physical chemistry courses is presented. Two pH meters are required and 10 -4 mol of AgNO 3 or AgOAc is consumed. The concentration cell, Ag(s) | Ag + (0.001 M) || Ag + (0.001 M) {pH electrode} | Ag(s), is used. The cell potential and pH are monitored as standard 0.1 M NaOH is titrated into the cathode compartment, precipitating Ag 2 O. The cathode pOH, pAg, and pK sp are computed at each point of the titration. The results illustrate theoretical expectation and are in excellent agreement with the literature.
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