Spectra of the real and imaginary parts of the refractive index m = n ' - in from 2.5 microm to 40 microm of ammonium sulfate, Sahara dust (as collected at Barbados), volcanic dust (pumice), and dust from a coalfired power plant are presented. With a peak absorption index n = 1.0 at 10 microm Sahara dust turns out to be the strongest absorber in the atmospheric window. The dispersion of n' is also very pronounced near 9 microm and 20 microm. Volcanic and coal-fire dust also absorb in the window region stronger than most of our earlier-investigated more normal aerosol fractions. The data for ammonium sulfate are compared with Remsberg's measurements on an aqueous solution.
The optical constants in the ir from lambda2.5 microm to 40 microm (4000-250 cm(-1)) of dry natural aerosol substances and of sea salt are presented. The aerosol substances were obtained from rain and snow water: dust and soot by sedimentation, and water soluble salts by evaporation. The spectra of the absorption index n' were derived from our published transmittance measurements of potassium bromide disks. The real part n of the refractive index was calculated from the specular reflectance at near normal incidence of disks of pure aerosol substance. The observed spectral features are being related to chemical constituents, notably sulfates and alcohol soluble organics. Optical constants of composite and wet aerosol are discussed. A simple model confirms the measured transmission of a coarse dry powder of water solubles and shows that the extinction by natural aerosol should have a minimum near 8 microm and a strong maximum near 9 microm.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.