We present a new approach to laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) U‐Pb dating of carbonates based on selection and pooling of pixels from 2‐D elemental and isotopic ratio maps. This image mapping technique is particularly useful for targeting subdomains in samples with complex geological histories. Key major and trace elements that are sensitive to detrital components, postformational fluid ingress, mineralogical changes, or diagenetic overprinting are measured along with the Pb and U isotopic data. Laser sampling is undertaken along successive linear rasters that are compiled into maps using the Monocle add‐on for Iolite, with one pixel in the map corresponding to one time slice of the time‐resolved signal. These element, element ratio, and isotope ratio maps can be overlain over photomicrographs or scanning electron microscopy images to spatially link compositional data to textural and structural features. The pixels corresponding to likely homogeneous age domains can be isolated by applying appropriate selection criteria (e.g., Th < 0.3 ppm, Mg/Ca < 0.004) and pooled into pseudo‐analyses using a proxy for the parent/daughter ratio (e.g., 207Pb/235U, 238U/208Pb) to retrieve the largest possible spread of the data points on isochron diagrams. The approach is best suited for analytical setups capable of rapidly or simultaneously scanning over a large mass range and can yield a precision of ±1% or better on quadrupole instruments depending on U concentration, 238U/204Pb, and age of the sample. The sample‐specific filtering criteria for selection and rejection of data and their rationale can be reported, resulting in more transparency with regard to data processing.
Conchostracans are one of the most common fossil animal groups of continental deposits from late Palaeozoic to modern times. Their habitats have ranged from perennial lakes of the Carboniferous and Early Permian to seasonal playa lakes and temporary ponds from the late Early Permian into the Triassic, where they could form mass occurrences. This, together with relatively high speciation rates, makes them ideal guide fossils, especially in otherwise fossil-poor wet and dry red beds. Based on material and data collected since the 1980s from both surface outcrops and well cores in central Europe, a preliminary conchostracan zonation is proposed. We used a conservative approach, erecting assemblage zones comprising two or three species instead of species-range zones with only one or, sometimes, two forms. Assemblage zones are more robust and provide more reliability for each delineated time interval. Isotopically dated occurrences of conchostracan zone species, or co-occurrences of conchostracans, insect zone species and marine index fossils such as conodonts and fusulinids, allow us to correlate our assemblage zones with the marine Standard Global Chronostratigraphic Scale.
The Central European Basin is very suitable for high-resolution multistratigraphy of Late Permian to Early Triassic continental deposits. Here, the well exposed transition of the lithostratigraphic Zechstein and Buntsandstein Groups of central Germany was studied for isotope-chemostratigraphy (δ 13 Corg, δ 13 Ccarb, δ 18 Ocarb), major-and trace-element geochemistry, magnetostratigraphy, palynology, and conchostracan biostratigraphy. The analyzed material was obtained from both classical key sections (abandoned Nelben clay pit, Caaschwitz quarries, Thale railway cut, abandoned Heinebach clay pit) and a recent drill core section (Caaschwitz 6/2012) spanning the Permian-Triassic boundary. The Zechstein-Buntsandstein transition consists of a complex sedimentary facies comprising sabkha, playalake, aeolian, and fluvial deposits of predominantly red-colored siliciclastics and intercalations of lacustrine oolitic limestones. The new data on δ 13 Corg range from-28.73 ‰ to-21.67 ‰ showing multiple excursions. Strongest negative shifts correlate to single intercalations of oolites and gray-colored clayey siltstones, while isotopically more heavy shifts correspond to an onset of palaeosoil overprint. The δ 13 Ccarb range from-9.69 ‰ to-1.34 ‰ with strongest variations recorded in dolomitic nodules from the Zechstein Group. A correlation of δ 18 Ocarb-values with the carbonate content is interpreted to reflect diagenesis. In contrast to sedimentary facies shifts across the Zechstein-Buntsandstein boundary, majorelement values used as proxy (CIA, CIA*, CIA-K) for palaeoclimate conditions indicate climatic stability. Trace-element data used for a geochemical characterization of the Late Permian to Early Triassic transition in central Germany indicate a decrease in the Rb at the Zechstein-Buntsandstein boundary.New palynological data obtained from the Caaschwitz quarry section reveal occurrences of Late Permian palynomorphs in the Lower Fulda Formation, while Early Triassic elements were recorded in the upper part of the Upper Fulda Formation. The present study confirms an onset of a normal-polarized magnetozone in the Upper Fulda Formation of the Caaschwitz quarry section supporting an interregional correlation of this crucial stratigraphic interval with the normal magnetic polarity of the basal Early Triassic known from marine sections in other regions. Based on a synthesis of the multistratigraphic data, the Permian-Triassic boundary is proposed to be placed in the lower part of the Upper Fulda Formation, which is biostratigraphically confirmed by the first occurrence date of the Early Triassic Euestheria gutta-Palaeolimnadiopsis vilujensis conchostracan fauna. Rare records of conchostracans reported from the siliciclastic deposits of the lower to middle Zechstein Group may point to its potential for further biostratigraphic subdivision of the Late Permian continental deposits.
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