Tubular and fibrous nanostructures of titanates have recently been synthesized and characterized. Three general approaches (template assisted, anodic oxidation, and alkaline hydrothermal) for the preparation of nanostructured titanate and TiO2 are reviewed. The crystal structures, morphologies, and mechanism of formation of nanostructured titanates produced by the alkaline hydrothermal method are critically discussed. The physicochemical properties of nanostructured titanates are highlighted and the links between properties and applications are emphasized. Examples of early applications of nanostructured titanates in catalysis, photocatalysis, electrocatalysis, lithium batteries, hydrogen storage, and solar‐cell technologies are reviewed. The stability of titanate nanotubes at elevated temperatures and in acid media is considered.
12Energy storage technologies provide an alternative solution to the problem of balancing power generation and power consumption. Redox flow cells are designed to convert and store electrical energy into chemical energy and release it in a controlled fashion when required. Many redox couples and cell designs have being evaluated. In this paper, redox flow systems are compared in the light of characteristics such as open circuit potential, power density, energy efficiency and charge-discharge behaviour. The key advantages and disadvantages of redox flow cells are considered while areas for further research are highlighted.
Redox flow batteries, which have been developed over the last 40 years, are used to store energy on the medium to large scale, particularly in applications such as load levelling, power quality control and facilitating renewable energy deployment. Various electrode materials and cell chemistries have been proposed; some of the successful systems have been demonstrated on a large-scale in the range of 10 kW–10 MW. Enhanced performance is attributable to the improvements in electrodes, separator materials and an increasing awareness of cell design. This comprehensive review provides a summary of the overall development of redox flow battery technology, including proposed chemistries, cell components and recent applications. Remaining challenges and directions for further research are highlighted
This review considers the literature published since 1994 on microbial and enzymatic biofuel cells. Types of biofuel cell are classified according to the nature of the electrode reaction and the nature of the biochemical reactions. The performance of fuel cells is critically reviewed and a variety of possible applications is considered. The current direction of development of biofuel cells is carefully analysed. While considerable chemical development of enzyme electrodes has occurred, relatively little progress has been made towards the engineering development biofuel cells. The limit of performance of biofuel cells is highlighted and suggestions for future research directions are provided.
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