Through experimental study, we reveal superlubricity as the mechanism of self-retracting motion of micrometer sized graphite flakes on graphite platforms by correlating respectively the lock-up or self-retraction states with the commensurate or incommensurate contacts. We show that the scale-dependent loss of self-retractability is caused by generation of contact interfacial defects.A HOPG structure is also proposed to understand our experimental observations, particularly in term of the polycrystal structure. The realisation of the superlubricity in micrometer scale in our experiments will have impact in the design and fabrication of micro/nanoelectromechanical systems based on graphitic materials. Nano-mechanical devices based on van de Waals forces in multi-walled carbon nanotubes (MWCNT) and HOPG (i.e., multilayered graphenes) have attracted intensive experimental and theoretical studies, owing to their superior properties, e.g., the nearly `freely' motion of inner shell inside the outer shell of a MWCNT [1,2,3], the MWCNT based oscillator with GHz resonance frequency [4], the extremely fast self-retraction motion of graphite flakes in HOPG islands [5] and so on. The role of the interlayer van de Waals interaction in driving the motion of such van de Waals devices has been well recognised and studied by various theoretical analysis and molecular dynamic simulations [3,4,6,7]. On the other hand, the interlayer van de Waals interactions also leads to potential corrugations due to the periodic atomic structures of the graphene layers, and in turn results in the interlayer friction/resistance force. The role of such friction force in the van de Waals micro/nano-mechanical devices, however, is largely overlooked and there is no experimental studies in micrometer scale up to now (except few scanning probe microscope (SPM) experiments with nanoscale sharp tip scanning on top of a graphene [8,9,10,11]). In this Letter, we will reveal the decisive role of such friction force in the van de Waals nano-mechanical devices. Our resultsshow that the superlubricity, as a result of the incommensurate contact of different graphene layers, is the necessary condition for the self-driven motion of CNT/graphene based micro/nanomechanical devices.Superlubricity is a phenomenon that friction force vanish or almost vanish when two solid surfaces are sliding over each other [12], and has attracted many attentions [13,14,15,16] since the introduction of the concept [17]. The structural incommensurate between two crystalline solid
Making small liquid droplets move spontaneously on solid surfaces is a key challenge in lab-on-chip and heat exchanger technologies. Here, we report that a substrate curvature gradient can accelerate micro- and nanodroplets to high speeds on both hydrophilic and hydrophobic substrates. Experiments for microscale water droplets on tapered surfaces show a maximum speed of 0.42 m/s, 2 orders of magnitude higher than with a wettability gradient. We show that the total free energy and driving force exerted on a droplet are determined by the substrate curvature and substrate curvature gradient, respectively. Using molecular dynamics simulations, we predict nanoscale droplets moving spontaneously at over 100 m/s on tapered surfaces.
The emergence of the field of nanofluidics in the last decade has led to the development of important applications including water desalination, ultrafiltration and osmotic energy conversion. Most applications make use of carbon nanotubes, boron nitride nanotubes, graphene and graphene oxide. In particular, understanding water transport in carbon nanotubes is key for designing ultrafiltration devices and energy-efficient water filters. However, although theoretical studies based on molecular dynamics simulations have revealed many mechanistic features of water transport at the molecular level, further advances in this direction are limited by the fact that the lowest flow velocities accessible by simulations are orders of magnitude higher than those measured experimentally. Here, we extend molecular dynamics studies of water transport through carbon nanotubes to flow velocities comparable with experimental ones using massive crowd-sourced computing power. We observe previously undetected oscillations in the friction force between water and carbon nanotubes and show that these oscillations result from the coupling between confined water molecules and the longitudinal phonon modes of the nanotube. This coupling can enhance the diffusion of confined water by more than 300%. Our results may serve as a theoretical framework for the design of new devices for more efficient water filtration and osmotic energy conversion devices.
We report STM-induced desorption of H from Si(100)-H(2×1) at negative sample bias. The desorption rate exhibits a power-law dependence on current and a maximum desorption rate at −7 V. The desorption is explained by vibrational heating of H due to inelastic scattering of tunneling holes with the Si-H 5σ hole resonance. The dependence of desorption rate on current and bias is analyzed using a novel approach for calculating inelastic scattering, which includes the effect of the electric field between tip and sample. We show that the maximum desorption rate at −7 V is due to a maximum fraction of inelastically scattered electrons at the onset of the field emission regime.
A sheared microscopic graphite mesa retracts spontaneously to minimize interfacial energy. Using an optical knife-edge technique, we report first measurements of the speeds of such self-retracting motion (SRM) from the mm/s range at room temperature to 25 m/s at 235°C [corrected]. This remarkably high speed is comparable with the upper theoretical limit found for sliding interfaces exhibiting structural superlubricity. We observe a strong temperature dependence of SRM speed which is consistent with a thermally activated mechanism of translational motion that involves successive pinning and depinning events at interfacial defects. The activation energy for depinning is estimated to be 0.1-1 eV.
The state of computer and networking technology today makes the seamless sharing of computing resources on an international or even global scale conceivable. Scientific computing Grids that integrate large, geographically distributed computer clusters and data storage facilities are being developed in several major projects around the world. This article reviews the status of one of these projects, Enabling Grids for E-SciencE, describing the scientific opportunities that such a Grid can provide, while illustrating the scale and complexity of the challenge involved in establishing a scientific infrastructure of this kind.
For in-situ measurements of the local electrical conductivity of well-defined crystal surfaces in ultrahigh vacuum, we have developed two kinds of microscopic four-point probe methods. One involves a "four-tip STM prober," in which four independently driven tips of a scanning tunneling microscope (STM) are used for measurements of four-point probe conductivity. The probe spacing can be changed from 500 nm to 1 mm. The other method involves monolithic micro-four-point probes, fabricated on silicon chips, whose probe spacing is fixed around several µm. These probes are installed in scanningelectron-microscopy/electron-diffraction chambers, in which the structures of sample surfaces and probe positions are observed in situ. The probes can be positioned precisely on aimed areas on the sample with the aid of piezoactuators. By the use of these machines, the surface sensitivity in conductivity measurements has been greatly enhanced compared with the macroscopic four-point probe method. Then the conduction through the topmost atomic layers (surface-state conductivity) and the influence of atomic steps on conductivity can be directly measured.
By combining conventional silicon microfabrication and direct three-dimensional growth using electron-beam induced carbon contamination, we have developed a scheme for fabricating nanotweezers with a gap of 25 nm. Four silicon oxide cantilevers with a spacing of 1.5 µm extending over an edge of a silicon support chip, were covered with a thin layer of metal. By focusing an electron beam at the ends of the cantilevers, narrow supertips grew from the substrate. Careful alignment of the substrate made the supertips converge to form a nanoscale gap. We demonstrate customization of the shape and size of the tweezer arms, using a simple scheme that allows conveniently fine-tuning of the tip features and the gap to within 5 nm. The supertips can be metallized subsequently, to be made conducting, without significantly affecting the shape of the tweezers. By applying a voltage on the outer electrodes with respect to the inner two electrodes, the gap can be opened and closed. This enables the device to grab and manipulate small particles, with the option of direct electrical measurement on the particle. The advantage of our approach is that no voltage difference is applied between the tweezer arms, making the device ideal for application with such fragile structures as organic objects.
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