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The dynamics of dissociation of the hydrogen molecular ion H 2 ϩ in an intense infrared ͑IR͒ field is studied by a series of wave packet simulations. In these simulations, the molecular ion is assumed to be instantly prepared at the initial time by a sudden ionization of the ground-state H 2 parent molecule, and a variety of frequency and intensity conditions of the laser field are considered. A new stabilization mechanism, called dynamical dissociation quenching, is found operative in the IR spectral range. In a time-resolved picture, this effect is shown to arise when a proper synchronization between the molecular motions and the laser field oscillations is ensured. In the Floquet, dressed molecule picture, the effect is related to interferences between the Floquet resonances that are excited initially by the nonadiabatic, sudden preparation of the ion. The Floquet analysis of the wave packets in this low frequency regime reveals important intersystem couplings between Floquet blocks, reflecting the highly multiphoton character of the dynamics.

[1] The Atmospheric Chemistry Experiment (ACE) onboard the Canadian Space Agency's SCISAT-1 satellite has been in orbit since August of 2003. Its broad objective is to study the problem of stratospheric ozone depletion, particularly in the Arctic. The main instruments are two spectrometers, one an infrared Fourier Transform Spectrometer and the other a dual optical spectrophotometer sensitive in the UV and visible. Also included are two filtered imagers used to measure altitude profiles of atmospheric extinction and detect thin clouds. The nominal center wavelengths of the filters are 525 nm for the visible (VIS) imager and 1020 nm for the near-infrared (NIR) imager. With the decommissioning of other satellite instruments used to monitor global aerosols [i.e., Stratospheric Aerosol and Gas Experiment II (SAGE II), SAGE III, Polar Ozone and Aerosol Measurement (POAM) III, Halogen Occultation Experiment (HALOE)], the imagers provide much needed continuity in this data record. The data product from the imagers is still, however, in a preliminary state. Funding restrictions in the prelaunch period were responsible for an incomplete characterization of the imagers' optics and electronics and prevented corrections being made for the problems found during testing. Postlaunch data analysis to correct for image artifacts is ongoing. A comparison with coincidental measurements from SAGE II shows that systematic errors from the preliminary analysis are within 5 and 20% for the VIS and NIR imagers, respectively, for uninverted profiles of optical depth. Despite the preliminary nature of the imager results, a paper describing the imagers and the initial operational data processing code is timely because the data are already being used.

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Details on the first linear arrays of 512x3 VO x microbolometers operating in space are reported. Arrays of this format are suited for remote sensing where relative motion between the spacecraft and target provides an inherent scanning mechanism. To take full advantage of the linear format, the array is built on a custom readout electronics that enables simultaneous integration of all pixels for scanning periods of up to 140 ms. The output signal from each pixel is digitized to 14 bits using a voltage-to-frequency conversion mechanism. Two arrays, integrated into two spectrally distinct radiometric packages, provide for coregistration of infrared images in three bands centered at 3.8, 10.85, and 11.85 μm for the retrieval of fire and sea surface temperatures. Analysis of the downlinked data confirms the reliable in-orbit operation and consistency with pre-launch characteristics for both arrays. Algorithms have been developed to perform post processing and absolute radiometric calibration of images in all bands. Image deconvolution using Wiener filtering was found effective in recovering the signal loss incurred in the active pixels when observing high temperature events. The in-flight gain and offset values were evaluated for all pixels by means of deep space measurements and cross calibration with reference spaceborne sensors. Preliminary assessment of the images calibrated using these values showed that they are in agreement with those retrieved from GOES sensor.