The formation of adsorbed surfactant layers consisting of a mesh or network of branched cylindrical aggregates on muscovite mica by several surfactant systems is described. The curvature of the adsorbed aggregates is varied by a variety of mechanisms that all generate morphologies between adsorbed cylinders and bilayers, and the resulting lateral structure is imaged by "soft contact" atomic force microscopy. We compare the direct images and Fourier transforms of the adsorbed layer structures, and relate them to those formed in bulk solution.
Magnetic resonance imaging (MRI) has been used to determine quantitatively one-dimensional proton concentration profiles in clay gels prepared from water/heavy water mixtures, taking into account the variations of spin-spin relaxation rate and other effects on the signal intensity. The method has been used to determine the diffusion coefficient of water in Laponite gels at macroscale, by following the diffusion of water from a volume of gel prepared with water into a volume of gel prepared with heavy water. The results have been compared with the self-diffusion coefficients at microscale obtained by pulsed gradient spin-echo (PGSE) NMR. Both results are in agreement in spite of the complex structure of the gel, but the reduction in diffusion coefficient as compared to bulk water is larger than predicted from effective medium theories.
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