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The unique optical and electronic properties of graphene make possible the fabrication of novel optoelectronic devices. One of the most exciting graphene characteristics is the tunability by gating which allows one to realize active optical devices. While several types of graphene-based photonic modulators have already been demonstrated, the potential of combining the versatility of graphene with subwavelength field confinement of plasmonic waveguides remains largely unexplored. Here we report fabrication and study of hybrid graphene–plasmonic waveguide modulators. We consider several types of modulators and identify the most promising one for telecom applications. The modulator working at the telecom range is demonstrated, showing a modulation depth of >0.03 dB μm−1 at low gating voltages for an active device area of just 10 μm2, characteristics which are already comparable to those of silicon-based waveguide modulators while retaining the benefit of further device miniaturization. Our proof-of-concept results pave the way towards on-chip realization of efficient graphene-based active plasmonic waveguide devices for optical communications.

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We study the photoresponsive behavior of thin films of supramolecular 4-nitro-4′-hydroxyazobenzenepoly(4-vinylpyridine) complexes. Hydrogen bonding between the phenol and pyridine moieties allows attaching a chromophore to essentially each repeat unit of the polymer, thereby suppressing macroscopic phase separation and crystallization. Moreover, the noncooperative nature of hydrogen bonding leads to random complexation of the chromophores to the polymer backbone, which enables a systematic study of the effect of chromophore concentration on the photo-orientation of the complexes. Two regimes are observed: Photoinduced birefringence increases linearly with the chromophore concentration until nominally every third polymer repeat unit is occupied. Beyond that concentration, a new regime is observed with a drastically steeper slope of increase. The latter regime is connected to the interplay between the formation of a hydrogen-bonded supramolecular complex and intermolecular interactions between the mesogenic chromophores. Such a behavior significantly enhances the birefringence at high concentrations and also leads to high remnant birefringence. Hence, the supramolecular approach yields a superior optical performance compared to guest-host polymers and even surpasses the properties of many covalently functionalized polymers, while still allowing modular tunability of the materials properties.