Structural features of very highly disordered 2:1 trioctahedral phyllosilicates from the Madrid Basin have been studied. Application of Fourier methods to XRD patterns shows that these materials consist of random kerolite-stevensite mixed-layered phases (R = 0) with 50–80% kerolite layers, and have a very small particle size with a mean of three unit-cells stacked in the c* direction. IR spectrum deconvolution in OH-stretching and librational modes seems to indicate five different types of water. Specific surface measurements (N2, BET) indicate anomalous high values (240–320 m2/g). These results suggest important catalytic and surface chemistry applications.

Contamination of aquatic systems with potentially toxic trace elements (PTEs) is a major problem throughout the world. The National Park Tablas de Daimiel (NPTD) is considered to make up one of the two most important wetlands in the Biosphere Reserve called "Wet Spot." Since PTEs are good indicator of the prevailing environmental conditions and possible contamination, soil samples collected from 43 sites were analyzed in order to investigate the levels and its distribution of these elements, in the inundated floodplain area of the NPTD wetland. In addition, some physicochemical parameters such as pH, electrical conductivity and organic matter were measured. The total concentrations of 32 trace elements were determined by X-ray fluorescence. The results show that there was accumulation of lead (Pb), tin (Sn), selenium (Se), antimony (Sb), copper (Cu), vanadium (V), nickel (Ni), zinc (Zn), arsenic (As), strontium (Sr) and zirconium (Zr)-in some cases at high concentrations. The interpolated maps showed that the distributions of some of these elements and in some cases the trend in spatial variability are pronounced and decrease from the inlet to the outlet. The values for some elements are higher than the reference values, which is consistent with contamination (some values are higher by a factor of more than 10 compared to the reference). In the case of iodine (I), the levels at some sample points are significantly more than ten times the reference; Se appears in the range from 1.0 to 9.8 mg/kg, with an average value of 3.1 mg/kg, and these can be considered as seleniferous soils. The concentrations found are consistent with the introduction in the wetland of pollution by human activities, such as agricultural non-point sources, uncontrolled fertilization over many years, treatment with urban wastewater and other possible sources.

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Castilla-La Mancha (central Spain) is a region characterized by significant agricultural production aimed at high-quality food products such as wine and olive oil. The quality of agricultural products depends directly on the soil quality. Soil geochemistry, including dispersion maps and the recognition of baselines and anomalies of various origins, is the most important tool to assess soil quality. With this objective, 200 soil samples were taken from agricultural areas distributed among the different geological domains present in the region. Analysis of these samples included evaluation of edaphological parameters (reactivity, electrical conductivity, organic matter content) and the geochemistry of major and trace elements by X-ray fluorescence. The dataset obtained was statistically analyzed for major elements and, in the case of trace elements, was normalized with respect to Al and analyzed using the relative cumulative frequency (RCF) distribution method. Furthermore, the geographic distribution of analytical data was characterized and analyzed using the kriging technique, with a correspondence found between major and trace elements in the different geologic domains of the region as well as with the most important mining areas. The results show an influence of the clay fraction present in the soil, which acts as a repository for trace elements. On the basis of the results, of the possible elements related with clay that could be used for normalization, Al was selected as the most suitable, followed by Fe, Mn, and Ti. Reference values estimated using this methodology were lower than those estimated in previous studies.

A precise evaluation of soil quality (SQ) is important for sustainable land use planning. This study was conducted to assess soil quality using multivariate approaches. An assessment of SQ was carried out in an area of Dakhla Oasis using two methods of indicator selection, i.e., total data set (TDS) and minimum data set (MDS), and three soil quality indices (SQIs), i.e., additive quality index (AQI), weighted quality index (WQI), and Nemoro quality index (NQI). Fifty-five soil profiles were dug and samples were collected and analyzed. A total of 16 soil physicochemical parameters were selected for their sensitivity in SQ appraising to represent the TDS. The principal component analysis (PCA) was employed to establish the MDS. Statistical analyses were performed to test the accuracy and validation of each model, as well as to understand the relationship between the used methods and indices. The results of principal component analysis (PCA) showed that soil depth, gravel content, sand fraction, and exchangeable sodium percentage (ESP) were included in the MDS. High positive correlations (r ≥ 0.9) occurred between SQIs calculated using TDS and/or MDS under the three models. Moreover, the findings showed highly significant differences (p < 0.001) among SQIs within and between TDS and MDS. Approximately 80 to 85% of the total study area based on TDS, as well as 70 to 75%, according to MDS, were identified as suitable soils with slight limitations on soil quality grade (Q3, Q2, and Q1), while the remaining 20 to 30% had high to severe limitations (Q4 and Q5). The highest sensitivity (SI = 2.9) occurred by applying WQI using MDS and indicator weights based on the variance of PCA. Furthermore, the highest linear regression value (R2 = 0.88) between TDS and MDS was recorded using the same model. Because of its high sensitivity, such a model could be used for monitoring SQ changes caused by agricultural practices and environmental factors. The findings of this study have significant guiding implications and practical value in assessing the soil quality using TDS and MDS in arid areas critically and accurately.

The essential features of the soils of a pilot zone in La Mancha (Central Spain), namely the Alcubillas municipability, have been characterized. The soil properties that may contribute to a better understanding of the impact of soil on grape production have also, been evaluated. For this, several soil profiles have been described and analyzed and the profiles have been mapped. The soils are mainly Entisols, Inceptisols and Alfisols, with their evolution controlled by the action of a xerophytic Mediterranean climate. Most of these soils have a loamy clay texture, with medium clay contents and sufficient nutrient contents (despite the low content in organic matter 1.39% and 1.04%, and the high concentrations of calcium carbonate 23.7% and 26.9% in the surface and subsurface horizons, respectively). Drainage problems were not observed and it can therefore be stated that the Alcubillas vineyards are based on a ‘terroir’ term for the production of high quality grapes. In general, the soils are not subjected to treatments to control possible diseases or pests and we have therefore postulated that the soils represent the ideal scenario to establish a distinctive zone and for the increasingly valued ecological and natural viticulture.