The predicted shortage of fossil fuels and related environmental concerns have recently attracted significant attention to scientific and technological issues concerning the conversion of biomass into fuels. First-generation biodiesel, obtained from vegetable oils and animal fats by transesterification, relies on commercial technology and rich scientific background, though continuous progress in this field offers opportunities for improvement. This review focuses on new catalytic systems for the transesterification of oils to the corresponding ethyl/methyl esters of fatty acids. It also addresses some innovative/emerging technologies for the production of biodiesel, such as the catalytic hydrocracking of vegetable oils to hydrocarbons. The special role of the catalyst as a key to efficient technology is outlined, together with the other important factors that affect the yield and quality of the product, including feedstock-related properties and various system conditions.
Reversible solid oxide cells can provide efficient and cost-effective scheme for electrical-energy storage applications. However, this technology faces many challenges from material development to system-level operational parameters , which should be tackle for practical purposes. Accordingly, this study focuses on developing novel robust artificial intelligence-based blackbox models to optimize operational variables of the system. A genetic-programming algorithm is used for Pareto modeling of reversible solid oxide cells in a multi-objective fashion based on experimental input-output data. The robustness of the obtained optimal model evaluated using Monte Carlo simulations technique. An optimization study adopted to optimize the operating parameters, such as temperature and fuel composition using a differential evolution algorithm. The objective functions that have been considered for Pareto multi-objective modeling process are training error and model complexity. In addition, the discrepancy between maximum and minimum output voltage in the whole operation of the system is chosen as the optimization process objective function. The robustness of the optimal trade-off model is shown in terms of statistical indices for varied uncertainty levels from 1 to 10%. The optimized operational condition based on the suggested model reveals optimal intermediate temperature of 762 °C and fuel mixture of about 29% H 2 , 25% H 2 O, and 14% CO.
Many African countries have vast biomass resources that could serve as feedstock for methane production through the adoption of commercial biogas plants. However, due to many inhibiting factors, these resources are under-utilised. This article reviews commercial biogas systems that treat organic waste from municipalities, large livestock farms, large plantations/crop farms, food/beverage production facilities, and other industries, to identify essential lessons which African countries could use to develop/disseminate such biogas systems. The review identified the critical barriers to commercial biogas development to be high initial capital costs, weak environmental policies, poor institutional framework, poor infrastructure and a general lack of willpower to implement renewable energy policies and set challenging targets. In African countries where feed-in-tariffs, quota obligations and competitive bidding programmes have been instituted, implementation has been poor, and most state-owned utilities have been unsupportive. Using knowledge from more experienced countries such as Germany and China, some key lessons have were identified. Among the key lessons is the need to institute and enforce environmental management policies to ensure that waste from medium and large livestock farms and industries are not disposed of indiscriminately, a tool China has recently used to promote commercial biogas plants to a high degree of success.
In 1989, the government of Ghana set in motion an electrification plan that aims to provide universal access to electricity within a 30-year period, from 1990 to 2020. About 25 years down the line, Ghana seems to be inching closer toward universal electrification. However, a number of challenges remain. As is the case in many other countries, urban communities have greater access to the national electricity grid than rural communities. Also, electricity generation in the country has not matched demand. This has resulted in load shedding/power rationing that has become the bane of the power sector in Ghana, negatively impacting all sectors of the economy and leading to economic losses. The low generation capacity is partly due to poor fuel supply to existing thermal power plants, meaning that installed capacity is often not available for use. This is coupled with low investment in transmission and distribution systems' infrastructure. Going forward, the government of Ghana would have to explore alternative ways of obtaining fuel, such as regasification, to solve the chronic issue of poor fuel supply for electricity generation. Distributed generation systems, using community mini-grid and off-grid systems are other alternatives that could be explored within the framework of the access agenda in order to reach the unserved poor located in remote rural communities.
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