This paper presents research on the influence of quartz deformation in aggregates for the development of the alkali-silica reaction in concrete and its relationship with silica dissolution. The study also compares these characteristics with the field behavior of such rocks in concrete. The paper proposes parameters to classify the different degrees of deformation of quartz. Transmission electron microscopy showed the presence of walls even in slightly deformed quartz, which indicate the presence of the internal paths available to react with the alkaline concrete pore solutions and point to the potential development of an alkali-silica reaction. The presence of the deformation bands in the quartz grains leads to the alkali aggregate reaction occurring more rapidly. The visible spectrophotometer test was performed to evaluate the dissolution potential of the different samples of deformed quartz, which confirmed that the reactivity of the quartz increases as the deformation of the crystalline structure increases. The parameters established in the present study could be verified by analyzing the behavior of reactive and innocuous aggregates from the buildings.
The main objective of this study was to evaluate the use of additives in producing foamed concrete blocks, which were made by totally replacing natural sand with civil construction waste (CCW). The concrete blocks were developed in accordance with an experimental design that used the complete factorial statistical method, for which three factors with different levels were considered: cement type (CP-V, CP II-Z, and CP II-F); use of additive (without additive, plasticizer, air entrainment, and superplasticizer) and foam amount (5.7%, 7.7%, and 9.5% of the total mass). The influence of each factor and the interactions between them were assessed on the following response variables: compressive strength, dry and saturated density, air voids, water absorption, and thermal conductivity. The results show that all factors had a significant influence on the variable response. For example, the use of the superplasticizer additive resulted in higher compressive strength, lower density, lower air void, and lower thermal conductivity. Finally, the use of additives had little influence on the response variables in relation to the other factors.
Defects in the crystalline structure of quartz facilitate the connection with the alkali hydroxides, since under a high alkalinity condition (e.g., in concrete), the Si-O bonds of quartz are easily broken. This study set out to investigate the influence of the deformation structures of quartz on its susceptibility to the alkali–silica reaction. A granite, a protomylonite, and a mylonite were selected for this study. Using optical microscopy, the quartz grains contained in these rocks were quantified and their texture characterized. The quartz samples extracted from the rocks were analyzed by magnetic nuclear resonance, to evaluate their potential for dissolving silica as well as changes in their atomic scale before and after the reaction with alkali hydroxides. These analyses were compared with the results of the accelerated mortar bar test. The study showed that the quartz with intense undulatory extinction and deformation bands denotes the most favorable condition to the development of the alkali–silica reaction. However, on an atomic scale, the slightly deformed grains were highly prone to react. Thus, in a high alkalinity condition, over a long period of time, any quartz tends to develop the alkali–silica reaction, regardless of the deformation degree of the grain.
Milled asphalt removed from old pavement carpets requires tenable handling easily reachable through its incorporation within other paving materials. This work deals with the effects of such incorporation to dry compacted concretes. Fine, intermediate, coarse and whole portions of milled asphalts were blended to a reference concrete. Mechanical tests disclosed remarkable losses on its strengths and modulus of elasticity; for the stereoscope and scanning microscopy pointed out impaired transition zones between the cement paste and the milled aggregates involved by thin asphalt films. Nevertheless, the mechanical results shown that the concretes with incorporated milled asphalt aggregates are suitable for use in pavement layers as bases and sub-bases even with reduced mechanical parameters.
Delayed Ettringite formation (DEF) is an internal expansive reaction that can damage concrete. DEF is strongly influenced by the temperature, above about 60-65°C, and other factors involving cement chemistry especially, but also its physical characteristics. The exposure environment over time also promotes a condition to increase deterioration from DEF. Expansions results from secondary ettringite formation are progressive and can lead concrete to microcracking impacting its performance and durability over time. Several concrete structures are pointed to be severely attacked by DEF, and test method as well a better comprehension on this pathology is necessary to promote specific and proper preventive measures to avoid future damages. Furthermore, compared to alkali-silica reaction, DEF occurs more readily and aggressively, and sometimes prematurely, depending on several factors, such as type of cement, concrete mix design, exposure conditions, among others. This paper involves an overall analysis of the behavior of concretes with two types of Portland cements (High early-strength cement and a Portland pozzolanic cement, with fly-ash) in relation to DEF process. Several data from a laboratory study where DEF was induced through a specific thermal curing procedure are presented and discussed. The analyses involved the assessment of physical, mechanical, and expansive properties besides microstructural monitoring of samples from concretes over time. These experiments allowed detecting high values of expansions from DEF (up to 1.2%) in the concrete without fly ash. The mechanical properties were severely impacted from this deleterious process; as expansions increased, losses in the mechanic and elastic properties were verified. Expansion levels in the order of 0.5% prompted remarkably high reductions and, at about 1% the losses were relevant for both strengths (tensile and compressive) and modulus of elasticity, of 60% and 80%, respectively, in the presence of cement without fly-ash. Concrete microstructure has indicated massive formations of ettringite as well as micro-cracking and the fragility of the cement matrix because of DEF. On the other hand, expansion up to 0.2% did not promote important negative effects on the properties of concrete, especially with the pozzolanic cement tested. Furthermore, an overall approach with several correlations between physical and mechanical properties was taken to obtain different levels of deterioration for a concrete presenting DEF.
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