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We present petrographic and mineralogical data for 21 mantle xenoliths (12 lherzolites, 8 wehrlites and 1 composite) selected from a suite of more than 70 samples collected from the Monticchio Formation, Mt. Vulture volcano, southern Italy. The xenoliths are rounded, coarse- to porphyroclastic-textured, and very fresh, with the following equilibrated mineral assemblages; olivine (Fo90–92), orthopyroxene (∼En89, Wo2.0), clinopyroxene (Mg90–92, 3–6% Al2O3, 1–1.5% Cr2O3), and chrome-spinel (14–20% MgO, ∼30–40% Cr2O3). Many xenoliths contain partial melt glasses and accessory sulphide (pentlandite) Some contain primary mica (phlogopite with ∼4% FeO, 1.8% Cr2O3, 1.4–2.8% TiO2) with slightly zoned rims (Fe-, Ti-, Al-enriched). One contains relics of garnet (pyrope; Mg84). Secondary veins in several xenoliths contain carbonate with significant Sr levels (∼0.5–1.0% SrO), occasional apatite and scarce melanite, all typical of carbonatites and presumably related to the host magma (melilitite/carbonatite). Although amphibole is a common megacryst in the same volcanic units, no primary amphibole was found in the xenoliths themselves. Calculated pressures and temperatures using a range of geothermometers/barometers give values of 14–22 kbar and 1050–1150°C. In particular, the En-Sp and Di-Sp thermo/barometers (Mercier, 1980) show a good positive correlation between P and T. The Monticchio xenoliths lie on the high-T side of an ‘oceanic’ geotherm. The xenolith geotherm is hotter than general heat flow values in this region at the current day (50 mWm−2) but it compares well with the high-pressure end of a typical alkaline continental rift.

The Tyrrhenian rift zone has been the site of widespread magmatism since late Tortonian times. A pronounced asymmetrical distribution, reflecting the tectonic structure, characterizes Italian magmatism. Sodic basalts occur on the western Tyrrhenian flank and transitional-MORB basalts occur in the Tyrhenian Sea. The eastern flank, however, is characterized by K-alkaline and HKto ultra-alkaline (e.g. carbonatites and melilitites) rocks. Major trace elements and isotopic compositions allow two major magmatic lineages to be identified: one relating to a non-radiogenic basaltic end-member and the other to a mantle endmember enriched in Ca, with high LILE/HFSE ratio and high Sr isotopic ratios. Their mantle sources are located within the lithosphere thermal boundary layer (TBL) and the metasomatized phlogopitecarbonate asthenosphere at the base of the TBL, respectively. The composition and spatial distribution of volcanism and relative mantle sources tend to map the geometry of the lithospheric mantle and to define a pronounced increase in depth from less than 60 km to about 100 km across the boundary between the thinned Tyrrhenian lithosphere and the Adriatic lithosphere. A mechanism of intracontinental passive rifting, which drives mantle upwelling, is sufficient to satisfy the petrological and geochemical constraints and the observed tectonic environment without requiring a subduction plane.

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