The utilization of fermentation media derived from waste and by-product streams from biodiesel and confectionery industries could lead to highly efficient production of bacterial cellulose. Batch fermentations with the bacterial strain Komagataeibacter sucrofermentans DSM (Deutsche Sammlung von Mikroorganismen) 15973 were initially carried out in synthetic media using commercial sugars and crude glycerol. The highest bacterial cellulose concentration was achieved when crude glycerol (3.2 g/L) and commercial sucrose (4.9 g/L) were used. The combination of crude glycerol and sunflower meal hydrolysates as the sole fermentation media resulted in bacterial cellulose production of 13.3 g/L. Similar results (13 g/L) were obtained when flour-rich hydrolysates produced from confectionery industry waste streams were used. The properties of bacterial celluloses developed when different fermentation media were used showed water holding capacities of 102–138 g·water/g·dry bacterial cellulose, viscosities of 4.7–9.3 dL/g, degree of polymerization of 1889.1–2672.8, stress at break of 72.3–139.5 MPa and Young’s modulus of 0.97–1.64 GPa. This study demonstrated that by-product streams from the biodiesel industry and waste streams from confectionery industries could be used as the sole sources of nutrients for the production of bacterial cellulose with similar properties as those produced with commercial sources of nutrients.

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Understanding the surface chemistry of electrode materials under gas environments is important in order to control their performance during electrochemical and catalytic applications. This work compares the surface reactivity of Ni/YSZ and LaSrCrFeO, which are commonly used types of electrodes in solid oxide electrochemical devices. In situ synchrotron-based near-ambient pressure photoemission and absorption spectroscopy experiments, assisted by theoretical spectral simulations and combined with microscopy and electrochemical measurements, are used to monitor the effect of the gas atmosphere on the chemical state, the morphology, and the electrical conductivity of the electrodes. It is shown that the surface of both electrode types readjusts fast to the reactive gas atmosphere and their surface composition is notably modified. In the case of Ni/YSZ, this is followed by evident changes in the oxidation state of nickel, while for LaSrCrFeO, a fine adjustment of the Cr valence and strong Sr segregation is observed. An important difference between the two electrodes is their capacity to maintain adsorbed hydroxyl groups on their surface, which is expected to be critical for the electrocatalytic properties of the materials. The insight gained from the surface analysis may serve as a paradigm for understanding the effect of the gas environment on the electrochemical performance and the electrical conductivity of the electrodes.

The solid oxide electrolysis cell (SOEC) technology has a huge potential for future mass production of hydrogen, mainly due to its high electrical-to-chemical energy conversion efficiency. However, the durability and the performance of SOEC devices are inferior to that of other competitive electrolysis technologies inhibiting the commercialization of SOECs. Despite the fact that Ni-based cermets are currently the most widely used cathode materials for SOEC, change of the nickel oxidation state has been accused as a major issue limiting the performance of these devices. In this work we provide operando experimental evidence of the active surface oxidation state and composition of nickel/doped-ceria cermets under water electrolysis conditions using ambient pressure X-ray photoelectron and near edge X-ray absorption fine structure spectroscopies, combined with quantitative spectra simulation. Remarkably under specific operational conditions, nickel is maintained in a partially oxidized state which, counterintuitive to the expected behavior, can be beneficial to the cell performance. This finding may initiate new improvement strategies for SOEC electrodes based on thorough optimization of the operational conditions, in order to engineer in situ the most propitious electrode configuration

Novel aromatic polyethers bearing polar pyridine units along the main chain and side cross-linkable propenyl groups have been successfully synthesized. Their properties relating to their ability to be used as polymer electrolyte membranes for high temperature fuel cell applications, were thoroughly investigated. Cross-linked membranes were obtained by thermal curing of the cross-linkable polymers with the use of a bisazide as the cross-linking agent. The glass transition temperatures of the cross-linked membranes were determined by dynamic mechanical analysis and found to be higher compared to the neat polymers proving the successful cross-linked network. The doping ability in phosphoric acid and the proton conductivity of the cross-linked membranes were higher compared to the noncross-linked analogues. Finally, membrane electrode assemblies (MEAs) were constructed and tested in a single cell at temperatures between 180 and 220 °C. The superior performance of the cross-linked membranes in combination with the operating stability at 200 °C for 48 h demonstrate the potential use of these materials as electrolytes for high temperature PEM fuel cells.

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Nickel-doped ceria nanoparticles (Ni0.1Ce0.9O2−x NPs) were fabricated from Schiff-base complexes and characterized by various microscopic and spectroscopic methods.