MoS2, as a catalyst, has attracted broad attention in recent years due to its high catalytic activity and low cost. However, MoS2 stacks readily, especially the one synthesized by calcination which is close to bulk, so it limits the number of exposed active site. Carbon materials possess excellent electrical conductivity and large surface area. In this paper, N‐doped hollow carbon sphere coated MoS2 (NHCS@MoS2) nanocomposites are synthesized via one‐step calcination treatment of the polypyrrole@(NH4)2MoS4 core shell structure directly. Compared with bare MoS2, the NHCS@MoS2 shows remarkably high electrocatalytic activity for hydrogen evolution with the overpotential of 190 mV to reach the current density of 10 mA cm−2. Both small tafel slope and Rct suggest that NHCS@MoS2 has a high hydrogen dissociation rate. Furthermore, it also exhibits excellent stability.
Graphene/nano-sulphur (S)/polyaniline (PANI) ternary nanocomposite was successfully synthesised and used as an electrode material for supercapacitors. In this process, the aniline was selected to accomplish two functions: In the first place, it served as a reducing agent, promoting the reduction of graphene oxide to graphene, without any additional reducing agent. In the second place, it played an important role in the formation of PANI. S nanoparticles were uniformly decorated on the graphene surface, and PANI covered the graphene/S surface. Furthermore, graphene and PANI prevented polysulphide species diffusion. The products were characterised by field-emission scanning electron microscopy, X-ray diffraction, Fourier-transform infrared spectra, X-ray photoelectron spectroscopy, Raman spectroscopy and electrochemical analysis. Owing to the specific combination of the advantages of graphene, nano-S and PANI, the composite exhibited outstanding electrochemical performance showing a specific capacitance as high as 619 F g−1 at a scan rate of 5 mV s−1 and excellent electrochemical stability with a retention of 77.9% (457 F g−1) of initial capacitance (586.8 F g−1) after 500 cycles at a current density of 1 A g−1.
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