Abstract. Climate change has the potential to increase surface ozone (O3) concentrations, known as the “ozone–climate penalty”, through changes to atmospheric chemistry, transport and dry deposition. In the tropics, the response of surface O3 to changing climate is relatively understudied but has important consequences for air pollution and human and ecosystem health. In this study, we evaluate the change in surface O3 due to climate change over South America and Africa using three state-of-the-art Earth system models that follow the Shared Socioeconomic Pathway 3-7.0 emission scenario from CMIP6. In order to quantify changes due to climate change alone, we evaluate the difference between simulations including climate change and simulations with a fixed present-day climate. We find that by 2100, models predict an ozone–climate penalty in areas where O3 is already predicted to be high due to the impacts of precursor emissions, namely urban and biomass burning areas, although on average, models predict a decrease in surface O3 due to climate change. We identify a small but robust positive trend in annual mean surface O3 over polluted areas. Additionally, during biomass burning seasons, seasonal mean O3 concentrations increase by 15 ppb (model range 12 to 18 ppb) in areas with substantial biomass burning such as the arc of deforestation in the Amazon. The ozone–climate penalty in polluted areas is shown to be driven by an increased rate of O3 chemical production, which is strongly influenced by NOx concentrations and is therefore specific to the emission pathway chosen. Multiple linear regression finds the change in NOx concentration to be a strong predictor of the change in O3 production, whereas increased isoprene emission rate is positively correlated with increased O3 destruction, suggesting NOx-limited conditions over the majority of tropical Africa and South America. However, models disagree on the role of climate change in remote, low-NOx regions, partly because of significant differences in NOx concentrations produced by each model. We also find that the magnitude and location of the ozone–climate penalty in the Congo Basin has greater inter-model variation than that in the Amazon, so further model development and validation are needed to constrain the response in central Africa. We conclude that if the climate were to change according to the emission scenario used here, models predict that forested areas in biomass burning locations and urban populations will be at increasing risk of high O3 exposure, irrespective of any direct impacts on O3 via the prescribed emission scenario.

Abstract. Volcanic eruptions that inject sulphur dioxide into the stratosphere have the potential to alter large-scale circulation patterns, such as the quasi-biennial oscillation (QBO), which can affect weather and transport of chemical species. Here, we conduct simulations of tropical volcanic eruptions using the UM-UKCA aerosol-climate model with an explicit representation of the QBO. Eruptions emitting 60 Tg of SO2 (i.e., 1815 Mt. Tambora-magnitude) and 15 Tg of SO2 (i.e., 1991 Mt. Pinatubo-magnitude) were simulated at the equator initiated during two different QBO states. We show that tropical eruptions delay the progression of the QBO phases, with the magnitude of the delay dependent on the initial wind shear in the lower stratosphere and a much longer delay when the shear is easterly than when it is westerly. The QBO response in our model is driven by vertical advection of momentum by the stronger tropical upwelling caused by heating due to the increased volcanic sulfate aerosol loading. Direct aerosol-induced warming with subsequent thermal wind adjustment, as proposed by previous studies, is found to only play a secondary role. This interpretation of the response is supported by comparison with a simple dynamical model. The dependence of the magnitude of the response on the initial QBO state results from differences in the QBO secondary circulation. In the easterly shear zone of the QBO, the vertical component of the secondary circulation is upward and reinforces the anomalous upwelling driven by volcanic aerosol heating, whereas in the westerly shear zone the vertical component is downward and opposes the aerosol-induced upwelling. We also find a change to the latitudinal structure of the QBO, with the westerly phase of the QBO strengthening in the hemisphere with the lowest sulfate aerosol burden. Overall, our study suggests that tropical eruptions of Pinatubo-magnitude or larger could force changes to the progression of the QBO, with particularly disruptive outcomes for the QBO if the eruption occurs during the easterly QBO shear.

Abstract. Climate change has the potential to increase surface ozone (O3) concentrations, known as the ‘ozone–climate penalty’, through changes to atmospheric chemistry, transport and dry deposition. In the tropics, the response of surface O3 to changing climate is relatively understudied, but has important consequences for air pollution, human and ecosystem health. In this study, we evaluate the change in surface O3 due to climate change over South America and Africa using 3 state-of-the-art Earth system models that follow the Shared Socioeconomic Pathway 3 7.0 emissions scenario from CMIP6. To quantify the changes driven by climate change alone, we evaluate the difference between end of the century predictions for simulations which include climate change and simulations with the same emissions scenario but with a fixed present-day climate. We find that by 2100, models predict an ozone–climate penalty in areas where O3 is already predicted to be high due to the impacts of precursor emissions, namely urban and biomass burning areas, although on average models predict a decrease in surface O3 due to climate change. We identify a small but robust positive trend in annual mean surface O3 over polluted areas. Additionally, during biomass burning seasons, seasonal mean O3 concentrations increase by 15 ppb (model range 12 to 18 ppb) in areas with substantial biomass burning such as the arc of deforestation in the Amazon. The ozone–climate penalty in polluted areas is shown to be driven by an increased rate of O3 chemical production, which is strongly influenced by NOx concentrations and is therefore specific to the emissions pathway chosen. Multiple linear regression finds the change in NOx concentration to be a strong predictor of the change in O3 production whereas increased isoprene emission rate is positively correlated with increased O3 destruction, suggesting NOx-limited conditions over the majority of tropical Africa and South America. However, models disagree on the role of climate change in remote, low-NOx regions, partly because of significant differences in NOx concentrations produced by each model. We also find that the magnitude and location of the ozone–climate penalty in the Congo basin has greater inter-model variation than in the Amazon, so further model development and validation is needed to constrain the response in central Africa. We conclude that if the climate were to change according to the emissions scenario used here, models predict that forested areas in biomass burning locations and urban populations will be at increasing risk of high O3 exposure.

Abstract. Volcanic eruptions that inject sulfur dioxide into the stratosphere have the potential to alter large-scale circulation patterns, such as the quasi-biennial oscillation (QBO), which can affect weather and transport of chemical species. Here, we conduct simulations of tropical volcanic eruptions using the UM-UKCA aerosol-climate model with an explicit representation of the QBO. Eruptions emitting 60 Tg of SO2 (i.e. the magnitude of the 1815 Mt. Tambora eruption) and 15 Tg of SO2 (i.e. the magnitude of the 1991 Mt. Pinatubo eruption) were initiated at the Equator during two different QBO states. We show that tropical eruptions delay the progression of the QBO phases, with the magnitude of the delay dependent on the initial wind shear in the lower stratosphere and a much longer delay when the shear is easterly than when it is westerly. The QBO response in our model is driven by vertical advection of momentum by the stronger tropical upwelling caused by heating due to the increased volcanic sulfate aerosol loading. Direct aerosol-induced warming with subsequent thermal wind adjustment, as proposed by previous studies, is found to only play a secondary role. This interpretation of the response is supported by comparison with a simple dynamical model. The dependence of the magnitude of the response on the initial QBO state results from differences in the QBO secondary circulation. In the easterly shear zone of the QBO, the vertical component of the secondary circulation is upward and reinforces the anomalous upwelling driven by volcanic aerosol heating, whereas in the westerly shear zone the vertical component is downward and opposes the aerosol-induced upwelling. We also find a change in the latitudinal structure of the QBO, with the westerly phase of the QBO strengthening in the hemisphere with the lowest sulfate aerosol burden. Overall, our study suggests that tropical eruptions of Pinatubo magnitude or larger could force changes to the progression of the QBO, with particularly disruptive outcomes for the QBO if the eruption occurs during the easterly QBO shear.

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