Thermal conductivity is an important material property for thermo-mechanical calculations, as mechanical properties strongly depend on the temperature and heat distribution in the manufactured parts. Although several suggestions for approximation formulae have been made, existing experimental data are rare and are not comparable due to different measurement methods. In addition, scarcely has the thermal conductivity in both the fiber direction and transverse direction been studied. The aim of the current research is to show the influence of carbon fiber volume content on the thermal conductivity of laminates. The values are then used to verify the micromechanical models used in the literature. A strong influence on the thermal conductivity could be determined. For the transverse thermal conductivity, the correlation was exponential; for the conductivity in the fiber direction, a linear correlation was found.
In this paper, the thermal and electrical conductivity and mechanical properties of fiber reinforced composites produced from nickel- and copper-coated carbon fibers compared to uncoated fibers are presented. The carbon fibers were processed by our prepreg line and cured to laminates. In the fiber direction, the thermal conductivity doubled from ~3 W/mK for the uncoated fiber, to ~6 W/mK for the nickel, and increased six times to ~20 W/mK for the copper-coated fiber for a fiber volume content of ~50 vol %. Transverse to the fiber, the thermal conductivity increased from 0.6 W/mK (uncoated fiber) to 0.9 W/mK (nickel) and 2.9 W/mK (copper) at the same fiber content. In addition, the electrical conductivity could be enhanced to up to ~1500 S/m with the use of the nickel-coated fiber. We showed that the flexural strength and modulus were in the range of the uncoated fibers, which offers the possibility to use them for lightning strike protection, for heatsinks in electronics or other structural heat transfer elements.
Additive manufacturing is on the verge of replacing established processes in dentistry, as it offers the possibility of manufacturing individual parts simply and cost-effectively. Due to its suitability for a wide variety of materials and, above all, its high precision, the focus is currently on stereolithographic processes. Intrinsic brittleness of the used multifunctional acrylic monomers remains however one of the major challenges. One promising concept is the use of block copolymers (BCPs) guaranteeing minor effects on 3D-printing processing and UV-curing due to initially at least partial solubility, and hence low viscosity impact. A polycaprolactone-polysiloxane (PCL-PDMS-PCL) triblock copolymer is synthesized via ring-opening polymerization of caprolactone and used in radical UV-cured methacrylic resin systems. Small angle X-ray scattering measurements reveal the self-assembly of the BCPs to objects of around 20 nm prior to curing. Subsequently, thermo-mechanical characterization is carried out by dynamic mechanical analysis, flexural testing, and fracture toughness measurements (K IC ). Transmission electron microscopy and scanning electron microscopy micrographs show a homogenous distribution of the BCPs and effective toughening via cavitation and shear yielding. The influence of the crosslink density on the toughness and the high effectiveness of block copolymers for improving fracture toughness is clearly shown.
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