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A test campaign was carried out to generate renewable hydrogen based on wood gas derived from the commercial biomass steam gasification plant in Oberwart, Austria. The implemented process consisted of four operation units: (I) catalyzed water−gas shift (WGS) reaction, (II) gas drying and cleaning in a wet scrubber, (III) hydrogen purification by pressure swing adsorption, and (IV) use of the generated biohydrogen (BioH 2 ) in a proton exchange membrane (PEM) fuel cell. For almost 250 h, a reliable and continuous operation was achieved. A total of 560 (L n dry basis (db) )/h of wood gas were extracted to produce 280 (L n db )/h of BioH 2 with a purity of 99.97 vol % db . The catalyzed WGS reaction enabled a hydrogen recovery of 128% (nḂ ioH 2 )/(nḢ 2 ,wood gas ) over the whole process chain. An extensive chemical analysis of the main gas components and trace components (sulfur, C x H y , and ammonia) was carried out. No PEM fuel cell poisons were measured in the generated BioH 2 . The only detectable impurities in the product were 0.02 vol % db of O 2 and 0.01 vol % db of N 2 .

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In many processes proposed for biorefineries, recycling procedures, and industrial or agricultural production processes, residue is generated which could be further transformed by thermochemical conversion via gasification. The technology of dual fluidized bed steam gasification is capable of producing a valuable product gas out of such residue. The generated nitrogen-free product gas can be used for heat and power production and is suitable for separating gases (e.g. hydrogen). However, if the product gas is cleaned, its use as syngas is more beneficial for manufacturing renewable chemical substances, like synthetic natural gas, methanol, Fischer-Tropsch liquids, or mixed alcohols. This paper presents the results of experimental research from gasification test runs of different biogenic fuels, carried out with an advanced 100 kW pilot plant over the last 5 years at TU Wien. The focus is to provide an overview of measured results validated by mass and energy balances and to present key calculated performance indicating key figures of the test runs. In this way, the influence of various operational parameters and the composition of the product gas are evaluated. The presented results form the basis for the proper design of suitable gas-cleaning equipment. Subsequently, the clean syngas is available for several synthesis applications in future biorefineries.