The purpose of our study is to compare the behavior of two reprocessed dental alloys (NiCr and CoCr) at different temperatures considering the idea that food and drinks in the oral cavity create various compositions at different pH levels; the novelty is the investigation of temperature effect on corrosion parameters and ion release of dental alloys. Electrochemical stability was studied together with morphology, elemental composition and ions release determination. The results obtained are in good concordance: electrochemistry studies reveal that the corrosion rate is increasing by increasing the temperature. From SEM coupled with EDS, the oxide film formed on the surface of the alloys is stable at low temperatures and a trend to break after 310K. ICP-MS results evidence that in accordance with increasing temperature, the quantities of ions released from the alloys immersed in artificial saliva also increase, though they still remain small, less than 20 ppm.
The aim of the paper is based on a combined approach to improve dental alloy performance using a new Ni-free Co–Cr composition with Mo, Nb and Zr and coated with an anodic oxidation film. The coated and uncoated samples were surface characterized by performing SEM (scanning electronic microscopy), XRD (X-rays diffraction) contact angle measurements and corrosion studies with open circuit potential, potentiodynamic polarization and EIS (impedance electrochemical spectroscopy) procedures. The SEM equipment with an EDX (Energy-dispersive X-ray spectroscopy) module indicated the sample morphology and the XRD investigations established the formation of the oxides. The electrochemical procedures were performed in Ericsson artificial saliva for coated samples in various conditions. Based on all the experiments, including the decrease in the hydrophobic character of the uncoated samples and the decrease in the hydrophilic values of the anodized alloys, the improved performance of the coated samples was established as a conclusion.
The aim of the present investigation is the electrochemical deposition of polypyrrole films from choline chloride-based ionic liquids at various potential, period times and simultaneously an indomethacin embedding and release. The electrodeposition films were performed on CoCr commercial type Wirobond C (WBC) and, Heraenium CE (Hera) using as electroprocedures for deposition cyclic voltammetry and chronoamperometry. The morphology of obtained films was investigated using scanning electron microscopy (SEM). An FT-IR investigation of CoCr alloys before and after electrodeposition was able to identify the presence of polymer and drug. The research included an evaluation of the hydrophilic character of all studied samples and their electrochemical characterization in Tanni Zuchi artificial saliva. In the electrochemical study, the following methods have been used: open circuit potential, electrochemical impedance spectroscopy and potentiodynamic polarization. Indomethacin release from the polymeric film was determined using UV-VIS spectra. Based on Fick’s law of diffusion and indomethacin release profile, a kinetic law for release was established and discussed.
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