This paper explores the evolution in the tensile strength of orange pruning fiber-reinforced polypropylene composites. The exploitation of these pruning's can effectively avoid incineration, with the consequence of CO2 emissions and fire risk, while extending the value chain of the agricultural industry. This biomass was subjected to three different treatments yielding mechanical, thermomechanical, and chemi-thermomechanical pulps. It was found that 20 to 50% of these pulps, together with a coupling agent, were used as polypropylene reinforcement. The evolution in the tensile strength and morphological properties of the fibers, and the effect of treatments on these properties were analyzed. A modified rule of mixtures (mROM) was used to analyze the micromechanical properties of the interface. In addition, the mechanical properties were weighted against the fiber treatment yields. Finally, factors to compute the net contribution of the fibers to the final strength of the composite materials were proposed.
Awareness on deforestation, forest degradation, and its impact on biodiversity and global warming, is giving rise to the use of alternative fiber sources in replacement of wood feedstock for some applications such as composite materials and energy production. In this category, barley straw is an important agricultural crop, due to its abundance and availability. In the current investigation, the residue was submitted to thermomechanical process for fiber extraction and individualization. The high content of holocellulose combined with their relatively high aspect ratio inspires the potential use of these fibers as reinforcement in plastic composites. Therefore, fully biobased composites were fabricated using barley fibers and a biobased polyethylene (BioPE) as polymer matrix. BioPE is completely biobased and 100% recyclable. As for material performance, the flexural properties of the materials were studied. A good dispersion of the reinforcement inside the plastic was achieved contributing to the elevate increments in the flexural strength. At a 45 wt.% of reinforcement, an increment in the flexural strength of about 147% was attained. The mean contribution of the fibers to the flexural strength was assessed by means of a fiber flexural strength factor, reaching a value of 91.4. The micromechanical analysis allowed the prediction of the intrinsic flexural strength of the fibers, arriving up to around 700 MPa, and coupling factors between 0.18 and 0.19, which are in line with other natural fiber composites. Overall, the investigation brightness on the potential use of barley straw residues as reinforcement in fully biobased polymer composites.
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