Carbon capture and storage is key for sustainable economic growth. CO2-enhanced oil recovery (EOR) methods are efficient practices to reduce emissions while increasing oil production. Although it has been successfully implemented in carbonate reservoirs, its effect on wettability and multiphase flow is still a matter of research. This work investigates the wettability alteration by carbonated water injection (CWI) on a coquina carbonate rock analogue of a Pre-salt reservoir, and its consequences in the flow of oil. The rock was characterized by routine petrophysical analysis and nuclear magnetic resonance. Moreover, micro-computed tomography was used to reconstruct the pore volume, capturing the dominant flow structure. Furthermore, wettability was assessed by contact angle measurement (before and after CWI) at reservoir conditions. Finally, pore-scale simulations were performed using the pore network modelling technique. The results showed that CWI altered the wettability of the carbonate rock from neutral to water-wet. In addition, the simulated relative permeability curves presented a shift in the crossover and imbibition endpoint values, indicating an increased flow capacity of oil after CWI. These results suggest that the wettability alteration mechanism contributes to enhancing the production of oil by CWI in this system.
Wettability is an important property in reservoir characterization. For the heterogeneous carbonate reservoirs in the Brazilian Pre-Salt, parameters that represent wettability are needed to obtain improved reservoir models. In this work, we applied contact angle measurements to analyze rock-fluid interactions between synthetic brine, crude oil from a Pre-Salt field and rocks and minerals with similar characteristics to the Pre-Salt formations. We studied the effects of aging time on different solid substrates. We found that, even though unaged quartz showed greater interaction with the high basic number oil than carbonates, it re mained water-wet for different aging times. On the other hand, calcite and coquinas had increasing contact angles with aging times and were strongly oil-wet after 30 days aging. This evidences that the interactions between acid compounds in the oil and basic sites in the substrate are strong enough to disrupt the water film after aging for 30 days. Therefore, under the Pre-Salt conditions studied in this work, these carbonate rocks and minerals should be considered as preferentially oil-wet.
Carbonate rocks host several large water and hydrocarbon reservoirs worldwide, some of them highly heterogeneous involving complex pore systems. Pre-salt reservoirs in the Santos Basin off the south-east coast of Brazil, are an example of such rocks, with much attention focused on proper characterization of their petrophysical and multiphase flow properties. Since it is very difficult to obtain rock samples (coquinas) from these very deep reservoirs, analogues from north-eastern Brazil are often used because of very similar geological age and petrophysical properties. We used a coquina plug from an outcrop in a quarry in northeast Brazil to perform a comprehensive set of analyses. They included Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), X-ray Diffraction (XRD), and micro-computed tomography (μCT) image acquisition using a series of pixel sizes, as well as direct permeability/porosity measurements. Some of the experimental data were collected from the plug itself, and some from a small sample of the rock slab, including thin sections. Results included the carbonate rock composition and the pore system at different scales, thus allowing us to reconstruct and model the porosity and absolute permeability of the coquina using 3D digital imaging and numerical simulations with pore network models (PNMs). The experimental and numerical data provided critical information about the well-connected pore network of the coquina, thereby facilitating improved predictions of fluid flow through the sample, with as ultimate objective to improve hydrocarbon recovery procedures.
ABSTRACT. Nuclear magnetic resonance (NMR) is a recognized petrophysical tool in the oil and gas industry to characterize reservoir rocks and fluids. In this study, the pore system of coquinas from a single bed of a quarry in the Morro do Chaves Formation was evaluated. These sedimentary rocks have been considered as a potential analogous to some Brazilian pre-salt reservoir rocks. The objective of this work was to characterize the porous system of coquinas in terms of total porosity and pore size distribution using low-field NMR. Conversion of T2 relaxation times to pore size radii was performed and literature cut-offs were applied for porosity partitioning. Coquinas were classified and ranked according to their percentage of macro, meso and micro porosity. This work verified quantitatively the pore system heterogeneities for the coquina samples and the variation in the layer from which they were extracted. The study provides some clues on lateral porosity and pore size variation in any reservoir for which this unit is an analogue.Keywords: Petrophysics, NMR, Total Porosity, Pore Size Distribution, Porosity Partitioning.RESUMO. Ressonância magnética nuclear (RMN) é uma técnica petrofísica reconhecida na indústria de óleo e gás pela sua capacidade de caracterizar rochas reservatório e seus fluidos saturantes. Neste estudo, foi avaliado o sistema poroso de coquinas pertencentes à uma camada de uma pedreira na Formação Morro do Chaves. Essas rochas sedimentares foram consideradas possíveis análogos de algumas rochas carbonáticas do pré-sal brasileiro. O objetivo do trabalho foi caracterizar o sistema poroso dessas coquinas em termos de porosidade total e distribuição de tamanho de poros utilizando RMN de baixo campo. Realizou-se a conversão dos tempos de relaxação T2 para raios de poro e empregou-se cut-offs da literatura para o particionamento da porosidade. As coquinas foram classificadas e ranqueadas de acordo com a sua porcentagem de macro, meso e micro poros. Verificou-se quantitativamente a heterogeneidade do sistema poroso das coquinas estudadas e a variação da camada sedimentar em que os plugues foram retirados. O estudo fornece informações sobre a variação lateral de porosidade e tamanho de poros para reservatórios que tenham a unidade estudada como análogo.Palavras-chave: Petrofísica, RMN, Porosidade Total, Distribuição do Tamanho de Poros, Particionamento da Porosidade.
CO2 injection is a well-known Enhanced Oil Recovery (EOR) technique that has been used for years to improve oil extraction from carbonate rock and other oil reservoirs. Optimal functioning of CO2 injection requires a thorough understanding of how this method affects the petrophysical properties of the rocks. We evaluated pore-scale changes in these properties, notably porosity and absolute permeability, following injection of CO2-saturated water in two coquina outcrop samples from the Morro do Chaves Formation in Brazil. The coquinas are close analogues of Pre-salt oil reservoirs off the coast of southern Brazil. The effects of carbonated water injection were evaluated using a series of experimental and numerical steps before and after coreflooding: cleaning, basic petrophysics, microtomography (microCT) imaging, nuclear magnetic resonance (NMR) analyses, and pore network modeling (PNM). Our study was motivated by an earlier experiment which did not show the development of a wormhole in the center of the sample, with a concomitant increase in permeability of the coquina as often noted in the literature. We instead observed a substantial decrease in the absolute permeability (between 71 and 77%), but with little effect on the porosity and no wormhole formation. While all tests were carried out on both samples, here we present a comprehensive analysis for one of the samples to illustrate changes at the pore network level. Different techniques were used for the pore-scale analyses, including pore network modeling using PoreStudio, and software developed by the authors to enable a statistical analysis of the pore network. Results provided much insight in how injected carbonated water affects the pore network of carbonate rocks.
Contents of this paper were reviewed by the Technical Committee of the 16 th International Congress of the Brazilian Geophysical Society and do not necessarily represent any position of the SBGf, its officers or members. Electronic reproduction or storage of any part of this paper for commercial purposes without the written consent of the Brazilian Geophysical Society is prohibited.
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