Amines Q 0120Cosolvent-Promoted Electrophilic Amination of Organozinc Reagents. -By use of a cosolvent, the amount of CuCN and waste is reduced and the yields are improved.-(DASKAPAN*, T.; YESILBAG, F.; KOCA, S.; Appl. Organomet. Chem. 23 (2009) 6, 213-218; Fac. Sci., Ankara Univ., TR-06100 Ankara, Turk.; Eng.) -Bartels 41-061
In this study, we aimed to develop a simple and efficient method for the electrophilic amination of organozinc reagents. For this reason, 12 cosolvents were screened in the electrophilic amination of ordinary organozinc reagents. By the use of a cosolvent, an easily applicable and high-yielding method for the preparation of arylamines by electrophilic amination of arylzinc reagents was developed.
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