Currently, one-dimensional all-inorganic CsPbX (X = Br, Cl, and I) perovskites have attracted great attention, owning to their promising and exciting applications in optoelectronic devices. Herein, we reported the exploration of superior photodetectors (PDs) based on a single CsPbI nanorod. The as-constructed PDs had a totally excellent performance with a responsivity of 2.92 × 10 A·W and an ultrafast response time of 0.05 ms, respectively, which were both comparable to the best ones ever reported for all-inorganic perovskite PDs. Furthermore, the detectivity of the PDs approached up to 5.17 × 10 Jones, which was more than 5 times the best one ever reported. More importantly, the as-constructed PDs showed a high stability when maintained under ambient conditions.
Tau protein—a member of the microtubule-associated protein family—is a key protein involved in many neurodegenerative diseases. Tau pathology in neurodegenerative diseases is characterized by pathological tau aggregation in neurofibrillary tangles (NFTs). Diseases with this typical pathological feature are called tauopathies. Parkinson's disease (PD) was not initially considered to be a typical tauopathy. However, recent studies have demonstrated increasing evidence of tau pathology in PD. A genome-wide association (GWA) study indicated a potential association between tauopathy and sporadic PD. The aggregation and deposition of tau were also observed in ~50% of PD brains, and it seems to be transported from neuron to neuron. The aggregation of NFTs, the abnormal hyperphosphorylation of tau protein, and the interaction between tau and alpha-synuclein may all contribute to the cell death and poor axonal transport observed in PD and Parkinsonism.
Development of novel hybrid photocatalysts with high efficiency and durability for photocatalytic hydrogen generation is highly desired but still remains a grand challenge currently. In the present work, we reported the exploration of ternary hybrid TiO2/CuO/Cu thoroughly mesoporous nanofibers via a foaming-assisted electrospinning technique. It is found that by adjusting the Cu contents in the solutions, the unitary (TiO2), binary (TiO2/CuO, TiO2/Cu), and ternary (TiO2/CuO/Cu) mesoporous products can be obtained, enabling the growth of TiO2/CuO/Cu ternary hybrids in a tailored manner. The photocatalytic behavior of the as-synthesized products as well as P25 was evaluated in terms of their hydrogen evolution efficiency for the photodecomposition water under Xe lamp irradiation. The results showed that the ternary TiO2/CuO/Cu thoroughly mesoporous nanofibers exhibit a robust stability and the most efficient photocatalytic H2 evolution with the highest release rate of ∼851.3 μmol g(-1) h(-1), which was profoundly enhanced for more than 3.5 times with respect to those of the pristine TiO2 counterparts and commercial P25, suggesting their promising applications in clean energy production.
Currently, all‐inorganic CsPbX3 (X = Br, I, and Cl) perovskites (IPs) are emerging as excellent candidate materials for exploring optoelectronic devices, due to their superior optical/electronic performances. However, their intrinsic poor stability greatly limits their practical applications. Here, a general strategy is reported for in situ growth of all‐inorganic perovskite nanocrystals (IPNCs) in polymer fibers with highly uniform size and spatial distribution, which is based on one‐step electrospinning of solutions containing IPs precursors and polymers. It is verified that the IPNCs of CsPbX3 can be uniformly encapsulated within the polymer fibers with finely tuned compositions, by rationally adjusting the ratios of PbX2 and CsX salts in the raw solutions. Consequently, the photoluminescence (PL) emissions of CsPbX3@polymer fibers can be readily tuned to cover the whole visible range. The obtained CsPbBr3@polymer fibers exhibit fundamentally improved water/thermal stabilities with a PL quantum yield (QY) of 48%. Their PL QY retains beyond 70% of its original value after being immersed in water for 192 h and maintains over 50% after being heated at 80 °C for 120 min. Furthermore, the light emitting diodes with high brightness based on CsPbBr3@polymer fibers are constructed, suggesting their promising applications.
Recently, preparation of mesoporous fibers has attracted extensive attentions because of their unique and broad applications in photocatalysis, optoelectronics, and biomaterials. However, it remains a great challenge to fabricate thoroughly mesoporous nanofibers with high purity and uniformity. Here, we report a general, simple and cost-effective strategy, namely, foaming-assisted electrospinning, for producing mesoporous nanofibers with high purity and enhanced specific surface areas. As a proof of concept, the as-fabricated mesoporous TiO2 fibers exhibit much higher photocatalytic activity and stability than both the conventional solid counterparts and the commercially available P25. The abundant vapors released from the introduced foaming agents are responsible for the creation of pores with uniform spatial distribution in the spun precursor fibers. The present work represents a critically important step in advancing the electrospinning technique for generating mesoporous fibers in a facile and universal manner.
Limited light harvesting
and charge collection are recognized as
grand challenges for the exploration of highly efficient TiO2 photoanodes. To overcome these intrinsic shortcomings, we reported
the designed photoanode based on TiO2 nanoarrays with both
hydrogenation treatment and surface decoration of carbon quantum dots
(CQDs) toward efficient photoelectrochemical water splitting. The
results revealed that hydrogenation treatment could cause the formation
of oxygen vacancies to suppress the recombination of photoinduced
carriers. Meanwhile, the decorated CQDs could not only play as the
electron reservoirs to trap photoinduced electrons but also remarkably
enhance the solar light harvesting due to their upconversion effect.
The as-fabricated photoanodes exhibited a large photocurrent density
of ∼3.0 mA/cm2 at 1.23 V versus reversible hydrogen
electrode under simulated sunlight, which was the highest one among
hydrogenated TiO2 photoanodes ever reported and was ∼6
times that of pristine analogues.
We report for the first time the synthesis of Al-doped 6H-SiC nanowires with high yield and high quality. The nanowires were obtained by the catalyst-assisted pyrolysis of polymeric precursors with FeCl2 as the catalyst. The doping concentrations were controlled by tailoring the Al concentrations in the precursors. It was observed that the Al dopants caused red-shifts of the photoluminescence bands. The results suggest a simple technique to synthesize Al-doped SiC nanomaterials in a controlled manner. The obtained nanowires could be useful for making optical and electronic nanodevices.
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