Herein we report the direct observation of C-H bond activation at an isolated mononuclear Pd(III) center. The oxidation of the Pd(II) complex (MeN4)PdII(neophyl)Cl (neophyl = -CH2C(CH3)2Ph; MeN4 = N,N′-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane) using...
Herein we
report the isolation, characterization, and photoreactivity of a stable Ni<sup>III</sup>
dichloride complex supported by a tetradentate pyridinophane N-donor ligand.
Upon irradiation, this complex undergoes an efficient photoreductive chlorine
elimination reaction, both in solution and the solid-state. Subsequently, the Ni<sup>III</sup>Cl<sub>2</sub>
<a>species can be regenerated via a reaction with PhICl<sub>2</sub></a>.
Herein we
report the isolation, characterization, and photoreactivity of a stable Ni<sup>III</sup>
dichloride complex supported by a tetradentate pyridinophane N-donor ligand.
Upon irradiation, this complex undergoes an efficient photoreductive chlorine
elimination reaction, both in solution and the solid-state. Subsequently, the Ni<sup>III</sup>Cl<sub>2</sub>
<a>species can be regenerated via a reaction with PhICl<sub>2</sub></a>.
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