Understanding the complicated interplay of the continuously evolving electrode materials in their inherent 3D states during the battery operating condition is of great importance for advancing rechargeable battery research. In this regard, the synchrotron X‐ray tomography technique, which enables non‐destructive, multi‐scale, and 3D imaging of a variety of electrode components before/during/after battery operation, becomes an essential tool to deepen this understanding. The past few years have witnessed an increasingly growing interest in applying this technique in battery research. Hence, it is time to not only summarize the already obtained battery‐related knowledge by using this technique, but also to present a fundamental elucidation of this technique to boost future studies in battery research. To this end, this review firstly introduces the fundamental principles and experimental setups of the synchrotron X‐ray tomography technique. After that, a user guide to its application in battery research and examples of its applications in research of various types of batteries are presented. The current review ends with a discussion of the future opportunities of this technique for next‐generation rechargeable batteries research. It is expected that this review can enhance the reader's understanding of the synchrotron X‐ray tomography technique and stimulate new ideas and opportunities in battery research.
The uncontrollable Li electrostripping and plating process that results in dendritic Li growth and huge volume change of Li anode limits the practicality of Li metal batteries (LMBs). To simultaneously address these issues, designing three‐dimensional (3D), lithiophilic and mechanically robust electrodes seems to be one of the cost‐effective strategies. Herein, a new 3D Li‐B‐C‐Al alloy anode is designed and fabricated. The prepared 3D alloy anode exhibits not only superior lithiophilicity that facilitates uniform Li nucleation and growth but also sufficient mechanical stability that maintains its structural integrity. Superior performance of the prepared 3D alloy is demonstrated through comprehensive electrochemical tests. In addition, non‐destructive and 3D synchrotron X‐ray computed tomography (SX‐CT) technique is employed to investigate the underlying working mechanisms of the prepared alloy anode. A unique twofold Li electrostripping and plating mechanism under different electrochemical cycling conditions is revealed. Lastly, improved performance of the full cells built with the 3D alloy anode and LiNi0.8Co0.1Mn0.1O2 (NCM811) cathode corroborate its potential application capability. Overall, the current work not only showcases the superiority of the 3D alloy as potential anode material for LMBs but also provides fundamental insights into its underlying working mechanisms that may further propel its research and development.
Abstract. According to the status quo of higher education and the requirement of quality education, this paper analyzes the status and function of physical education in quality education, points out the serious consequences of neglecting the quality of physical education in universities, and puts forward the reform strategies of universities' physical education under the background of quality education. The specific strategies include: constantly enrich the content of physical quality education, fully reflect the essential characteristics of quality education, innovative teaching model to meet the needs of future career, science and technology into the campus quality education, fully learn from foreign advanced physical education ideas, build a vibrant quality education system of physical education and the intuition of physical education under modern educational technology.
Lithium
metal, the most promising anode material, is receiving
increasing interest owing to its high theoretical capacity (3860 mA
h g–1) and low negative potential (−3.04
V vs. standard hydrogen electrode). However, the uneven Li dissolution/deposition
behavior causes a degraded cycle stability and safety issues, thus
seriously restricting the application of Li-metal batteries (LMBs).
Separator modification is one of the most versatile and feasible approaches
to overcome this problem. In this study, polypropylene (PP) separators
are prepared and coated with an inert hexagonal boron nitride (h-BN)
layer, which can provide sufficient ion transport channels and physical
protection. The h-BN@PP separator exhibits a remarkable effect on
the regulation of the diffusion and nucleation of Li+ to
realize a homogeneous Li microstructure, thereby reducing the voltage
polarization and improving the cycle performance of the battery. All
LMBs equipped with the modified separators exhibit excellent cycling
stabilities. The Li|Li symmetric cell exhibits a stable cycling for
over 2300 h with a polarization voltage of 13 mV. In conclusion, the
modified h-BN@PP separator has significant potential for stabilizing
various Li metal anodes, which strongly promotes the applications
of advanced LMBs.
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