Environmentally friendly synthetic methodologies have gradually been implemented as viable techniques in the synthesis of a range of nanostructures. In this work, we focus on the application of green-chemistry principles to the synthesis of complex metal oxide and fluoride nanostructures. In particular, we describe advances in the use of the molten-salt synthetic methods, hydrothermal protocols, and template-directed techniques as environmentally sound, socially responsible, and cost-effective methodologies that allow us to generate nanomaterials without the need to sacrifice sample quality, purity, and crystallinity, while allowing control over size, shape, and morphology.
We report, for the first time, utilizing a rotating ring‐disc electrode (RRDE) assembly for detecting changes in the local pH during aqueous CO2 reduction reaction (CO2RR). Using Au as a model catalyst where CO is the only product, we show that the CO oxidation peak shifts by −86±2 mV/pH during CO2RR, which can be used to directly quantify the change in the local pH near the catalyst surface during electrolysis. We then applied this methodology to investigate the role of cations in affecting the local pH during CO2RR and find that during CO2RR to CO on Au in an MHCO3 buffer (where M is an alkali metal), the experimentally measured local basicity decreased in the order Li+ > Na+ > K+ > Cs+, which agreed with an earlier theoretical prediction by Singh et al. Our results also reveal that the formation of CO is independent of the cation. In summary, RRDE is a versatile tool for detecting local pH change over a diverse range of CO2RR catalysts. Additionally, using the product itself (i.e. CO) as the local pH probe allows us to investigate CO2RR without the interference of additional probe molecules introduced to the system. Most importantly, considering that most CO2RR products have pH‐dependent oxidation, RRDE can be a powerful tool for determining the local pH and correlating the local pH to reaction selectivity.
Magnesium and its alloys are promising biodegradable biomaterials but are still challenging to be used in person with high levels of blood glucose or diabetes. To date, the influence of glucose on magnesium degradation has not yet been elucidated, this issue requires more attention. Herein, we present pure Mg exhibiting different corrosion responses to saline and Hank’s solutions with different glucose contents, and the degradation mechanism of pure Mg in the saline solution with glucose in comparison with mannitol as a control. On one hand, the corrosion rate of pure Mg increases with the glucose concentration in saline solutions. Glucose rapidly transforms into gluconic acid, which attacks the oxides of the metal and decreases the pH of the solution; it also promotes the absorption of chloride ions on the Mg surface and consequently accelerates corrosion. On the other hand, better corrosion resistance is obtained with increasing glucose content in Hank’s solution due to the fact that glucose coordinates Ca2+ ions in Hank’s solution and thus improves the formation of Ca-P compounds on the pure Mg surface. This finding will open up new avenues for research on the biodegradation of bio-Mg materials in general, which could yield many new and interesting results.
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