We study the performance of quantum absorption refrigerators, paradigmatic autonomous quantum thermal machines, and reveal central impacts of strong couplings between the working system and the thermal baths. Using the reaction coordinate quantum master equation method, which treats system-bath interactions beyond weak coupling, we discover that reshaping of the window of performance is a central outcome of strong system-bath couplings. This alteration of the cooling window stems from the dominant role of parameter renormalization at strong couplings. We further show that strong coupling admits direct transport pathways between the thermal reservoirs. Such beyond-second-order transport mechanisms are typically detrimental to the performance of quantum thermal machines. Our study reveals that it is inadequate to claim for either a suppression or an enhancement of the cooling performance at strong coupling-when analyzed against a single parameter and in a limited domain. Rather, a comprehensive approach should be adopted so as to uncover the reshaping of the operation window.
Whether genuine quantum effects, particularly quantum coherences, can offer an advantage to quantum devices is a topic of much interest. Here, we study a minimal model, the three-level V system coupled to two heat baths, and investigate the role of quantum coherences in heat transport in both the transient regime and in the nonequilibrium steady-state. In our model, energy is exchanged between the baths through two parallel pathways, which can be made distinct through the nondegeneracy of excited levels (energy splitting $\Delta$) and a control parameter $\alpha$, which adjusts the strength of one of the arms. Using a nonsecular quantum master equation of Redfield form, we succeed in deriving closed-form expressions for the quantum coherences and the heat current in the steady state limit for closely degenerate excited levels. By including three ingredients in our analysis: nonequilibrium baths, nondegeneracy of levels, and asymmetry of pathways, we show that quantum coherences are generated and sustained in the V model in the steady-state limit if three conditions, conjoining thermal and coherent effects are {\it simultaneously} met: (i) The two baths are held at different temperatures. (ii) Bath-induced pathways do not interfere destructively. (iii) Thermal rates do not mingle with the control parameter $\alpha$ to destroy interferences through an effective local equilibrium condition. Particularly, we find that coherences are maximized when the heat current is suppressed. Although we mainly focus on analytical results in the steady state limit, numerical simulations reveal that the transient behavior of coherences {\it contrasts} the steady-state limit: Large long-lived transient coherences vanish at steady state, while weak short-lived transient coherences survive, suggesting that different mechanisms are at play in these two regimes. Enhancing either the lifetime of transient coherences or their magnitude at steady state thus requires the control and optimization of different physical parameters.
Standard quantum master equation techniques, such as the Redfield or Lindblad equations, are perturbative to second order in the microscopic system–reservoir coupling parameter λ. As a result, the characteristics of dissipative systems, which are beyond second order in λ, are not captured by such tools. Moreover, if the leading order in the studied effect is higher-than-quadratic in λ, a second-order description fundamentally fails even at weak coupling. Here, using the reaction coordinate (RC) quantum master equation framework, we are able to investigate and classify higher-than-second-order transport mechanisms. This technique, which relies on the redefinition of the system–environment boundary, allows for the effects of system–bath coupling to be included to high orders. We study steady-state heat current beyond second-order in two models: The generalized spin-boson model with non-commuting system–bath operators and a three-level ladder system. In the latter model, heat enters in one transition and is extracted from a different one. Crucially, we identify two transport pathways: (i) System’s current, where heat conduction is mediated by transitions in the system, with the heat current scaling as j q ∝ λ2 to the lowest order in λ. (ii) Inter-bath current, with the thermal baths directly exchanging energy between them, facilitated by the bridging quantum system. To the lowest order in λ, this current scales as j q ∝ λ4. These mechanisms are uncovered and examined using numerical and analytical tools. We contend that the RC mapping brings, already at the level of the mapped Hamiltonian, much insight into transport characteristics.
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