Components and structures working in the marine environment are exposed to high stresses attributable to the action of wind, waves, and tides. Moreover, they have to face hostile and severe environmental conditions during their lifetime, being placed in the splash zone if not even submerged in saltwater. The application of polymer composites in marine systems has been the focus of intensive studies in the last decades, highlighting potential benefits given by the replacement of several components, such as ship hulls, propeller blades, wind, and tidal turbine blades, to cite but a few. The present paper reports the latest advances in this area, addressing the applications of advanced composites in ships and ship components, offshore oil and gas composites, marine renewable energy and underwater repairing.

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The Cold Gas Dynamic Spray technology, generally referred as Cold Spray, is a relatively new additive manufacturing technique able to produce fully dense coatings through the deposition of particles on a substrate. Fine powders are accelerated to high velocity and projected onto a substrate, upon impact with the target surface, conversion of kinetic energy to plastic deformation occurs and the solid particles deform and bond together. During the cold spray deposition process, the particles remain in a solid state during the deposition, resulting in high-quality coatings with low residual stresses and oxide inclusions. The relative lower process temperatures allow the cold spray to manufacture coatings on high temperature-sensitive materials. It could also be a valid method for deposition of a wide variety of materials, from metallic alloys up to ceramics and composites. Depending on the materials employed as substrate and coating, different bonding mechanisms can occur during the deposition. The present review aims to summarise the main bonding theories proposed up to now for the cold spray, focusing on both the particle deformation behaviour during the contact with the surface and the interfacial bonding mechanisms. The available theories for different substrate/coating configurations will be discussed and compared. The effects of deposition parameters, the substrate's surface and microstructure of feedstock powders on the bonding mechanism will also be discussed.

The aim of the present work is to investigate the feasibility and effects of a selective post-deposition laser treatment on titanium coatings. Commercially pure titanium grade 2 powders were deposited by means of a cold spray process on aluminum alloy AA2024-T3 sheets. The surface treatment of the coating was realized using a 220 W diode laser. The influence of heat input and dimensional features of coating layer and substrate was assessed by an experimental campaign conducted following a design of experiments approach. Optical and scanning electron microscopy analysis of the microstructure of the deposited and treated material as well as micro hardness measurements showed the formation of a compact layer of titanium oxide on the coating surface and the preservation of the temper state of the aluminum substrate

In this paper, a selective laser post-deposition on pure grade II titanium coatings, cold-sprayed on AA2024-T3 sheets, was experimentally and numerically investigated. Morphological features, microstructure, and chemical composition of the treated zone were assessed by means of optical microscopy, scanning electron microscopy, and energy dispersive X-ray spectrometry. Microhardness measurements were also carried out to evaluate the mechanical properties of the coating. A numerical model of the laser treatment was implemented and solved to simulate the process and discuss the experimental outcomes. Obtained results highlighted the key role played by heat input and dimensional features on the effectiveness of the treatment.

Cold Gas Dynamic Spray is an emerging coating technology based on the use of a supersonic gas jet to accelerate (up to 1000 m/s) and to impact a powder, with size ranging from 1 to 50 μm in diameter, on a substrate. Due to the high speed, during the impact, the powder undergoes a severe plastic deformation such that it adheres on the substrate. Thanks to this method, it is possible to produce up to fully dense metallic coatings on substrates of different materials. With this technology, different kinds of powder (metals, polymers, ceramics, composite materials and nanocrystalline powders) or their mixing can be deposited. Among the various possible powders that can be deposited by cold spray, titanium is one of the most attractive materials thanks to its potential applications. A titanium layer produced onto a softer materials (i.e. aluminium alloys) could improve both the corrosion resistance and the wear properties of the components. However, the coating made with this technique could be affected by several problems, such as porosity, high roughness and low mechanical properties. A possible solution for this issues is the use of laser remelting post-deposition treatment. The present investigation deals with the application of a continuous wave diode laser in order to change the coating properties and metallographic structure. With this aim, laser remelting of a titanium cold sprayed layer were carried out on samples of grade 2 titanium alloy, 5 mm thick, obtained by cold spray technique, by using a 220 W diode laser at different scan speed. In order to avoid the influence of the particular substrate, the laser remelting process was carried after the detachment of the coating from the substrate. After laser treatments, light and SEM microscopy were carried out to analyze the geometry of remelted zone and the evolution of its microstructure morphology. Moreover, micro-hardness measurements were made to evaluate the mechanical properties. Three different metallurgical structures corresponding to the remelted zone, the heat affected zone and base material were observed. The remelted zone showed an elliptical shape, with a depth up to 0.7 mm and a martensitic microstructure. Furthermore, in this zone, hardness higher than the base material (more than threefold) was found. In conclusion, it is possible to affirm that the laser remelting is a promising technique to improve the superficial properties of titanium cold sprayed layers

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