A strip of a liquid crystal elastomer doped with a near-infrared dye with one side crosslinked monodomain and the other crosslinked polydomain along the thickness behaves like a multifunctional photoactuator without the need for a support. A flat strip with two ends fixed on substrate surface forms a moving bump under laser scanning, which can be used as light-fueled conveyor to transport an object. Cutting off and laser scanning the bump with two free ends makes a soft and flexible millimeter-scale crawler that can not only move straight and climb an inclined surface, but also undergo light-guided turning to right or left as a result of combined out-of-plane and in-plane actuation. Based on the self-shadowing mechanism, with one end of the strip fixed on substrate surface, it can execute a variety of autonomous arm-like movements under constant laser illumination, such as bending-unbending and twisting, depending on the laser incident angles with respect to the strip actuator.
Smart microstructured materials enable functions such as actuation, detection, transportation, and sensing with potential applications ranging from robotics and photonics to biomedical devices. Of the many materials systems, liquid crystal polymer networks (LCN) are fascinating owing to their ability to exhibit reversible macroscopic deformation driven by a molecular order–disorder phase transition. LCN have been increasingly explored for their utility in the design and fabrication of smart actuating devices capable of complex shape changes or motions upon external stimulation of humidity, heat, light, and other stimuli, and recent studies in this field show that their actuation complexity can be enriched and actuation performance enhanced by having some sort of microstructures. Herein, the recent progress in microstructured actuation of LCN materials with substructures in scale ranging from micrometer to millimeter is reported, placing the emphasis on the main approaches to generating a microstructure in LCN, which include patterned LC director fields, patterned chain crosslinking in LCN with uniaxial orientation of mesogens, 3D/4D printing, and replica molding. The potential applications in microstructured 3D actuators and devices as well as functional LCN surfaces are also highlighted, with an outlook on important issues and future trends in smart microstructured LCN materials and actuators.
Photoresponsive actuators based on semicrystalline poly(ethylene-co-vinyl acetate) (EVA) loaded with small amounts of gold nanoparticles (AuNPs) are described. Upon absorption of light (532 nm), the heat released by the AuNPs raises the temperature in the irradiated region to T to melt crystallites with lower melting temperatures (T
Liquid crystalline elastomers (LCEs) have been actively investigated as stimuli‐controlled actuators and soft robots. The basis of these applications is the ability of LCEs to undergo a reversible shape change upon a liquid crystalline (LC)‐isotropic phase transition. Herein, we report the synthesis of a novel LCE based on a side‐chain liquid crystalline polymer (SCLCP). In contrast to known LCEs, this LCE exhibits a striking anomalous shape change. Subjecting a mechanically stretched monodomain strip to LC‐disorder phase transition, both the length and width of the strip contract in isotropic phase, and both elongate in LC phase. This thermally induced behaviour is the result of a subtle interplay between the relaxation of polymer main chain oriented along the stretching direction and the disordering of side‐group mesogens oriented perpendicularly to the stretching direction. This finding points out potential design of LCEs of this peculiar type and possible applications to exploit.
A porous liquid‐crystalline network (LCN), prepared by using a template method, was found to exhibit peculiar actuation functions. The creation of porosity makes the initially hydrophobic LCN behave like a hydrogel, capable of absorbing a large volume of water (up to ten times the sample size of LCN). When the amount of absorbed water is relatively small (about 100 % swelling ratio), the porous LCN displays anisotropic swelling in water and, in the same time, the retained uniaxial alignment of mesogens ensures a thermally induced shape change associated with a LC‐isotropic phase transition. Combining the characteristic actuation mechanisms of LCN (order–disorder transition of mesogens) and hydrogel (water absorption), such porous LCNs can be explored for versatile stimuli‐triggered shape transformations. Moreover, the porosity enables loading/removal/reloading of functional fillers such as ionic liquids, photothermal dyes and fluorophores, which imparts the porous LCN actuator with reconfigurable functions such as ionic conductivity, light‐driven locomotion, and emissive color.
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