The aim of this work was to prepare hydroxyapatite coatings (HAp) by a sol-gel method on Ti6Al4V alloy and to study the bioactivity, biocompatibility and corrosion protection behaviour of these coatings in presence of simulated body fluids (SBFs). Thermogravimetric/Differential Thermal Analyses (TG/DTA) and X-ray Diffraction (XRD) have been applied to obtain information about the phase transformations, mass loss, identification of the phases developed, crystallite size and degree of crystallinity of the obtained HAp powders. Fourier Transformer Infrared Spectroscopy (FTIR) has been utilized for studying the functional groups of the prepared structures. The surface morphology of the resulting HAp coatings was studied by Scanning Electron Microscopy (SEM). The bioactivity was evaluated by soaking the HAp-coatings/Ti6Al4V system in Kokubo’s Simulated Body Fluid (SBF) applying Inductively Coupled Plasma (ICP) spectrometry. 3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyl tetrazolium bromide (MTT) and Alamar blue cell viability assays were used to study the biocompatibility. Finally, the corrosion behaviour of HAp-coatings/Ti6Al4V system was researched by means of Electrochemical Impedance Spectroscopy (EIS). The obtained results showed that the prepared powders were nanocrystalline HAp with little deviations from that present in the human bone. All the prepared HAp coatings deposited on Ti6Al4V showed well-behaved biocompatibility, good bioactivity and corrosion protection properties.

This work researches the protective behaviour of silane based organic-inorganic hybrid coatings on AZ31 and AZ61 magnesium alloy substrates during exposure to 0.6 M NaCl solutions. An attempt is made to determine possible relationships between the degradation of the sol-gel film during its exposure and composition of the metal substrate. Results indicated that the sol-gel coated AZ61 substrate tends to develop corrosion slower than the sol-gel coated AZ31 substrate, tendency that can change by prolonging exposure time. After the curing process, the sol-gel coating formed on the AZ61 substrate is far more perfect, uniform and protective than that which results on the AZ31 substrate, behaviour attributed to the high protective effect of the pre-existing oxide film on the surface of the AZ61 alloy. After several days' immersion, a clear inhibitive effect of the corrosion products formed during the test is observed in the case of the sol-gel coated AZ31, but not with the coated AZ61 alloy substrate, a 2 phenomenon explained by the carbonate enrichment observed by XPS (X-ray photoelectron spectroscopy).

An attempt was made to estimate the corrosion rate of AZ31 and AZ61 magnesium alloys immersed in 0.6 M NaCl during long-term exposure using electrochemical impedance spectroscopy (EIS). The EIS results were compared with the corrosion rate independently assessed by the hydrogen evolution test. A correlation was established between the integration of the polarization resistance (R p ) and charge transfer resistance (R t ) over time, as evaluated by EIS and hydrogen gas measurements. Regardless of the immersion time, a strong link was found between the R t and R p values determined by EIS. This relation seems to depend on the composition of the alloy. The influence of immersion time on the estimated corrosion rate reliability was investigated. The typical deviations of the measurement methods are apparently decreasing upon prolonging the immersion time. No significant errors were obtained in the measurement of the corrosion rate when using R t or R p determined by EIS with their corresponding "apparent" Stern-Geary coefficient values compared with the real values determined by gravimetric measurements.

In order to elucidate the corrosion mechanism of Magnesium (Mg), assess its corrosion rate and evaluate the viability of effective corrosion protection methods, a number of different and complementary techniques are required. Aqueous corrosion is, in nature, an electrochemical process and as such electrochemical methods represent a powerful tool for the study of Mg corrosion. In this chapter the main electrochemical techniques used to study the corrosion of Mg are reviewed along with other simple non-electrochemical methods such as weight loss and hydrogen evolution measurements. The electrochemical techniques covered in this review include conventional DC and AC electrochemical techniques and the latest advances in local electrochemical methods for the evaluation and characterization of Mg corrosion. Each technique presented will be discussed, and its major advantages and drawbacks for the study of Mg corrosion will be commented. Applications range from studies of influence of the impurities in catalytic activity of high purity Mg towards hydrogen evolution, the determination of corrosion rate for Mg and Mg alloys by electrochemical methods and electrochemical study of sol-gel films as pretreatment for Mg alloys.

No abstract

No abstract

The influence of the presence of hydrogen bubbles adhered to the corroding specimen surface on the EIS estimations of corrosion rate of magnesium alloys is considered. The EIS corrosion rates for AZ31 specimens exposing a small area were four times higher than the real values determined by gravimetric or hydrogen evolution measurements. In contrast, no significant differences in the corrosion rate have been observed in the case of the AZ61 specimens. A progressive deterioration in the protective properties of the corrosion products layer formed during the test was observed only on AZ31 specimens exposing a small area.

No abstract