Surface-enhanced Raman spectroscopy (SERS) sensing of DNA bases by plasmonic nanopores could pave a way to novel methods for DNA analyses and new generation single-molecule sequencing platforms. The SERS discrimination of single DNA bases depends critically on the time that a DNA strand resides within the plasmonic hot spot. In fact, DNA molecules flow through the nanopores so rapidly that the SERS signals collected are not sufficient for single-molecule analysis. Here, we report an approach to control the residence time of molecules in the hot spot by an electro-plasmonic trapping effect. By directly adsorbing molecules onto a gold nanoparticle and then trapping the single nanoparticle in a plasmonic nanohole up to several minutes, we demonstrate single-molecule SERS detection of all four DNA bases as well as discrimination of single nucleobases in a single oligonucleotide. Our method can be extended easily to label-free sensing of single-molecule amino acids and proteins.
We propose a design for an universal absorber, characterized by a resonance frequency that can be tuned from visible to microwave frequencies independently of the choice of the metal and the dielectrics involved. An almost perfect absorption up to 99.8% is demonstrated at resonance for all polarization states of light and for a very wide angular aperture. These properties originate from a magnetic Fabry-Perot mode that is confined in a dielectric spacer of λ/100 thickness by a metamaterial layer and a mirror. An extraordinary large funneling through nano-slits explains how light can be trapped in the structure. Simple scaling laws can be used as a recipe to design ultra-thin perfect absorbers whatever the materials and the desired resonance wavelength, making our design truly universal.
An original ZnO nanowire (NW) architecture has been developed, entirely based on a soft chemistry approach, and thoroughly assessed through optical measurements and electromagnetic simulations. This architecture relies on the photoimprinting of a sol–gel ZnO‐based photosensitive seed layer combined with the subsequent localized hydrothermal growth of ZnO NWs. The optimization of the elaboration protocol has been shown to lead to uniform and reproducible linear and periodic gratings of ZnO NWs with a width/pitch of 2/4 µm. The NW gratings are compared with full‐covered samples (NWs coating) elaborated from a nonimprinted seed layer. A morphological study reveals that NW gratings present a peculiar hedgehog‐like profile. Standard and angle‐resolved photoluminescence studies demonstrate that the ZnO NWs visible emission is strongly modified by the presence of NW gratings and that its red part is directionally extracted and enhanced by a factor of up to 2. The electromagnetic simulations performed for both samples highlight the role of the gratings acting as coupled microcavities that boost the ZnO emission through light localization and diffractive mechanisms. It enables the extraction of the resonant photons at specific angles and wavelengths.
Plasmonic behavior in the far-infrared (IR) and terahertz (THz) ranges can facilitate a lot of applications in communication, imaging or sensing, security, and biomedical domains. However, simple scaling laws cannot be applied to design noble metal-based plasmonic systems operating at far-IR or THz frequencies. To overcome this issue, we numerically and experimentally explore the plasmonic properties in the spectral range between 25 and 40 μm (12 and 7.5 THz) of metal-insulator-metal (MIM) antennas made of InAsSb a highly Si-doped semiconductor. We demonstrate that these MIM antennas sustain a gap plasmon mode that is responsible for high light absorption. By tracking this peculiar plasmonic signature for various antennas' widths, we prove that Si-doped InAsSb microstructures realized on large areas by laser lithography and the wet etching process are a low cost, reproducible, and readily CMOS compatible approach.
Plasmonic nanoantennas are promising sensing platforms for detecting chemical and biological molecules in the infrared region. However, integrating fragile biological molecules such as proteins on plasmonic nanoantennas is an essential requirement in the detection procedure. It is crucial to preserve the structural integrity and functionality of proteins while attaching them. In this study, we attached lactose permease, a large membrane protein, onto plasmonic nanoantennas by means of the nickel-nitrile triacetic acid immobilization technique. We followed the individual steps of the immobilization procedure for different lengths of the nanoantennas. The impact of varying the length of the nanoantennas on the shape of the vibrational signal of the chemical layers and on the protein spectrum was studied. We showed that these large proteins are successfully attached onto the nanoantennas, while the chemical spectra of the immobilization monolayers show a shape deformation which is an effect of the coupling between the vibrational mode and the plasmonic resonance.
We experimentally demonstrate an ultrastrong coupling regime between a gap plasmon and phonon in metallic-insulator-metallic antennas at far-infrared frequencies. These plasmonic antennas made of a silicondoped semiconductor (InAsSb) are versatile structures able to reveal the polaritonic modes due to the hybridization of a gap plasmon and phonon. The anticrossing behavior featuring the ultrastrong coupling is properly studied by varying the width of the metallic antenna array. The gap-plasmon resonance supported by the antennas is shown to be particularly sensitive to the presence of phonons in the GaSb insulator. The experimental data demonstrate a giant Rabi splitting of 30% of the GaSb transverse optical phonon energy and are in good agreement with both electromagnetic and semiclassical calculations.
A dielectric transmittance filter composed of subwavelength grating sandwiched between two few-layers distributed Bragg reflectors (DBRs) is proposed with the aim of being compatible with CMOS technology and to be tunable by lithographic means of the grating pattern without the need of thickness changes, in the broad spirit of metamaterials. The DBR mirrors form a Fabry-Perot (FP) cavity whose resonant frequency can be tuned by changing the effective refractive index of the cavity, here, by tailoring the in-plane filling factor of the grating. The structure has been studied and designed by performing numerical simulations using Fourier Modal Method (FMM). This filter proves to have high broad angular tolerance up to ±30˚. This feature is crucial for evaluating the spectral performance of narrow-band filters especially the so-called Ambient light sensors (ALS). By analyzing the transmittance spectral distributions in the band diagram, it is found that the angular tolerance is due to coupling between the FP and the guided mode inside the cavity in analogy to resonances occurring within multimode periodic waveguides in a different context.
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