The quantification of groundwater NO loading associated with a specific field or set of management practices so that groundwater quality improvements can be objectively assessed is a major challenge. The magnitude and timing of NO export from a single agricultural field under raspberry ( L.) production were investigated by combining high-resolution groundwater NO concentration profiles (sampled using passive diffusion samplers) with Darcy's flux estimation at the field's down-gradient edge (based on field-measured hydraulic gradients and laboratory-estimated hydraulic conductivity). Annual recharge estimated using Darcy's law (1002 mm) was similar to that obtained using two other approaches. The similarity in the rate of Cl applied to the field and the estimated export flux over the 1-yr monitoring period (51 vs. 56 kg Cl ha) suggested the mass flux estimation approach was robust. An estimated 80 kg NO-N ha was exported from the agricultural field over the 1-yr monitoring period. The greatest monthly groundwater mass flux exported was observed in February and March (∼11 kg NO-N ha), and was associated with NO leached from the soil zone during the onset of precipitation in the previous autumn. Provided the groundwater recharged from the field of interest can be isolated within a vertical profile, this approach is an effective method for obtaining spatially integrated estimates of the magnitude and timing of NO loading to groundwater.

The Abbotsford-Sumas Aquifer is a permeable, unconfined aquifer in British Columbia, Canada, where raspberry (Rubus idaeus L.) production is an important source of groundwater NO 3 contamination. Renovation of raspberry fields (i.e., canes chopped, soil tilled and fumigated, and spring manure application prior to replanting), which typically occurs every 6 to 10 yr in response to decreased crop vigor, has been suggested as a possible cause of significant interannual variation in groundwater NO 3 concentrations. This study used high-resolution passive diffusion sampling to quantify the magnitude and timing of NO 3 loading to shallow groundwater from a commercial raspberry field during a 6-yr (2009-2015) monitoring period after crop renovation. After renovation, the annual NO 3 loading increased from ?95 kg N ha −1 in Year 1 to ?245 kg N ha −1 in Year 2 and decreased to ?85 kg N ha −1 in Year 3. The average annual NO 3 loading from Years 4 to 6 (72 kg N ha −1 ) was assumed to reflect annual loading without a renovation effect, and the increased loading during Years 1 to 3 was attributed to renovation. Renovation contributed an estimated 33 to 23% of total groundwater NO 3 from this field for a 6-to 10-yr renovation cycle. Most of the NO 3 loading associated with renovation occurred in Year 2 and was attributed to the manure application. The increased NO 3 loading after renovation likely contributes to the spatial and temporally varying NO 3 patterns observed in the aquifer. Reducing manure applications during renovation and decreasing renovation frequency have the potential to decrease the groundwater NO 3 concentration.