The present study is carried out to remove chromium and turbidity from tannery wastewater using the electrocoagulation process with aluminum electrodes. This experimental study is carried out using a batch system. The applied pilot comprises a reactor containing two parallel metal electrodes (Al). The latter are connected as monopolar, and a different potential is applied between them. Several working parameters, such as applied potential difference, electrolysis time, active electrode surface, interelectrode distance, and the pH of the medium have been studied to achieve higher removal efficiency. The treatment reached a maximum reduction of 99% for turbidity and 93% for chromium under the following conditions: 15 V applied potential difference, 45 cm2 electrode surface, 1 cm interelectrode distance, pH 6.1 raw water, and a contact time of 90 min. Given the treatment efficiency obtained in this study, electrocoagulation process has the potential to be used for the cost-effective removal of wastewater pollutants.
The objective of this study is the removal of chromium from tannery wastewater by electrosorption on carbon prepared from lignocellulosic natural residue "peach stones' thermally treated. The followed steps for obtaining coal in chronological order were: cleaning, drying, crushing and finally its carbonization at 900°C. The characterization of the carbon material resulted in properties comparable to those of many coals industrially manufactured. The study of the dynamic adsorption of chromium on the obtained material resulted in a low removal rate (33.7%) without applied potential. The application of negative potentials of -0.7 V and -1.4 increases the adsorption of chromium up to 90% and 96% respectively. Whereas a positive potential of +1.4V allows desorption of the contaminant of 138%.
In the last years, much attention has been focused on the use of low-cost adsorbents for the removal of heavy metals from wastewater. Raw biosorbent waste is a cheap and environmentally friendly material that provides good cost-benefit for the industries that use it. The objective of this study is to improve the feasibility of raw local peach stones (RPS) waste for the removal of hexavalent chromium from aqueous solution. The characterization of this raw biomaterial has been performed using various analytical techniques such as FTIR, SEM and XRD. In batch adsorption experiments the adsorption parameters optimized were pH 2, adsorbent dose 4 g/L, equilibrium contact time 240 min, initial Cr (VI) concentration 30 mg/ L and temperature 30°C. The removal percentage of Cr(VI) was 97 % at pH 2.The adsorption equilibrium was well explained by the Freundlich isotherm and the process followed the pseudo-second order kinetics. Thermodynamic parameters specify the spontaneous and endothermic nature of biosorption process. Desorption study was carried out with NaOH (0.1, 0.5, and 1M) solutions. Investigations carried out proved that RPS is a good potential and ecofriendly biosorbent for the treatment of toxic hexavalent chromium in aqueous solutions.
Raw biosorbent waste is a cheap and environmentally friendly material that provides good cost-benefit for the industries that use it. The objective of this study is to improve the feasibility of raw local peach stones (RPS) waste for the removal of hexavalent chromium from aqueous solution using column system. The characterization of the adsorbent (RPS) was done by using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The impact of various parameters such as flow rate (1.5,3 and 5 ml/min) and height bed (1,2 and 3 cm) on Cr(VI) adsorption onto RPS were investigated. Two models were proposed to illustrate column breakthrough curve obtained at different flow rates and bed heights. The obtained experimental results showed a better adsorption efficiency at a low flow rate (1.5 ml/min) and a bed height of 3cm. Thus this work provides the high potential of raw peach stones (RPS) for the removal of Cr(VI) ions from aqueous solution.
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