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Pharmaceuticals have been widely found in wastewater. Among them, diclofenac was detected at the highest frequency; in this study, the commercial activated carbon was used to remove diclofenac from synthetic wastewater. Various testing methods were applied to evaluate the efficiency of the activated carbon for removing diclofenac from residues wastewater such as scanning electron microscopy (SEM), Brunauer, Emmett and Teller (BET), and Energy Dispersive Spectroscopy (EDS). the operating conditions were determined by using a batch reactor with various parameters such as different pH, diclofenac concentration, and different mass of activated carbon. the result of operations conditions was: pH 5, diclofenac concentration is 1000 mg/l mass of activated carbon is 500gm/L, While, the difference of initial Ibuprofen concentration, flow rate, and bed depth was determined by packed bed reactor, it was found 2cm for bed height, and flow rate 25 l/hr, Diclofenac concentration, 625mg/l. from adsorption equilibrium and with Langmuir and Freundlich models, the kinetic constants were determined, also shown the pseudo-first-order gave the best result, and more suitable for the removal of Diclofenac by adsorbed activation carbon.

The current paper studies the viability of using a Batch reactor, by five types of Al-Fe pillared clay that prepared from five regions in Iraq for phenol degradation in synthetic wastewater. The operation condition study through variables in (pH, pressure, temperature, pillared load, phenol load). The findings have illustrated that phenol degradation could be increase via incrementing temperature, pressure, pillared load and degrease in phenol load. Phenol good degradation proportion which was 97 %, has been achieved at optimum proportion (pH= 3.9, temperature = 150 °C, pressure = 3.5 MPa, in addition to phenol concentration = 500 mg/l). The two models power-law and Langmuir−Hinshelwood have been used   to study the catalytic kinetics of the phenol degradation. From results shown the activation energy for every response equivalent to (37114.014 j/mol) for Anbar (37795, 48783.9, 36628, 40785 j/mol) for Erbil, Mosul, Baghdad and Basra respectively. It was proved that the reaction in this study is under kinetics control.

The current paper studies the viability of using a Batch reactor, by five types of Al-Fe pillared clay that prepared from five regions in Iraq for phenol degradation in synthetic wastewater. The operation condition study through variables in (pH, pressure, temperature, pillared load, phenol load). The findings have illustrated that phenol degradation could be increase via incrementing temperature, pressure, pillared load and degrease in phenol load. Phenol good degradation proportion which was 97 %, has been achieved at optimum proportion (pH= 3.9, temperature = 150 °C, pressure = 3.5 MPa, in addition to phenol concentration = 500 mg/l). The two models power-law and Langmuir−Hinshelwood have been used   to study the catalytic kinetics of the phenol degradation. From results shown the activation energy for every response equivalent to (37114.014 j/mol) for Anbar (37795, 48783.9, 36628, 40785 j/mol) for Erbil, Mosul, Baghdad and Basra respectively. It was proved that the reaction in this study is under kinetics control.