The phenomenological Ginzburg-Landau theory and the charge conservation directly lead to the finite Higgs-mode generation and vanishing charge-density fluctuation in the second-order optical response of superconductors at clean limit. Nevertheless, recent microscopic theoretical studies of the second-order optical response, apart from the one through the gauge-invariant kinetic equation [Yang and Wu, Phys. Rev. B 100, 104513 (2019)], have derived a vanishing Higgs-mode generation but finite charge-density fluctuation at clean limit. We resolve this controversy by re-examining the previous derivations with the vector potential alone within the path-integral and Eilenbergerequation approaches, and show that both previous derivations contain mathematical flaws. After fixing these flaws, a finite Higgs-mode generation through the drive effect of vector potential is derived at clean limit, exactly recovering the previous result from the gauge-invariant kinetic equation as well as Ginzburg-Landau theory. By further extending the path-integral approach to include electromagnetic effects from the scalar potential and phase mode, in the second-order response, a finite contribution from the drive effect of scalar potential to the Higgs-mode generation at clean limit as well as the vanishing charge-density fluctuation are derived, also recovering the results from the gauge-invariant kinetic equation. Particularly, we show that the phase mode is excited in the second-order response, and exactly cancels the previously reported unphysical excitation of the charge-density fluctuation, guaranteeing the charge conservation.

Spin−orbit coupling (SOC) is a fundamental physical interaction, which describes how the electrons' spin couples to their orbital motion. It is the source of a vast variety of fascinating phenomena in nanostructures. Although in most theoretical descriptions of high-temperature superconductivity SOC has been neglected, including this interaction can, in principle, revise the microscopic picture. Here by preforming energy-, momentum-, and spin-resolved spectroscopy experiments we demonstrate that while probing the dynamic charge response of the FeSe monolayer on strontium titanate, a prototype two-dimensional high-temperature superconductor using electrons, the scattering cross-section is spin dependent. We unravel the origin of the observed phenomenon and show that SOC in this two-dimensional superconductor is strong. We anticipate that such a strong SOC can have several consequences on the electronic structures and may compete with other pairing scenarios and be crucial for the mechanism of superconductivity.

author claimed that the formula in our work is immediately derivable from the transfer matrix formalism using only the factoring out cosine function. In the response, we demonstrate that the formula presented in our original paper is not the same as that proposed in the comment. It is difficult to obtain our formula by the method given in the comment. We also respond to some other criticisms of the original work raised in the comment.

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