A general one-pot solvothermal process was explored to prepare BiOX (X = Cl, Br, I) powders by employing
ethylene glycol as the solvent. The as-prepared BiOX powders were characterized by X-ray powder diffraction,
scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron
microscopy, UV−vis diffuse reflectance spectroscopy, and nitrogen sorption. The resulting BiOX samples
were phase-pure and of hierarchical microspheres consisting of nanoplates. The band gaps of the as-prepared
powders were estimated to about 3.22, 2.64, and 1.77 eV for BiOCl, BiOBr, and BiOI, respectively. On the
basis of characterization results, we proposed a possible process for the growth of hierarchical BiOX nanoplate
microspheres. Moreover, we evaluated their photocatalytic activities on the degradation of methyl orange
and compared them with TiO2 (Degussa, P25) under UV−vis light irradiation and C-doped TiO2 under visible
light (λ > 420 nm) irradiation, respectively. It was found that all the BiOX samples were photocatalytically
active and BiOI exhibited excellent activity under both UV−vis and visible light irradiation. The resulting
hierarchical BiOX nanoplate microspheres are very promising photocatalysts for degrading organic pollutants
and other applications.
Semiconductor photocatalysis is a trustworthy approach to harvest clean solar light for energy conversions, while state-of-the-art catalytic efficiencies are unsatisfactory because of the finite light response and/or recombination of robust charge carriers. Along with the development of modern material characterization techniques and electronic-structure computations, oxygen vacancies (OVs) on the surface of real photocatalysts, even in infinitesimal concentration, are found to play a more decisive role in determining the kinetics, energetics, and mechanisms of photocatalytic reactions. This Review endeavors to clarify the inherent functionality of OVs in photocatalysis at the surface molecular level using 2D BiOCl as the platform. Structure sensitivity of OVs on reactivity and selectivity of photocatalytic reactions is intensely discussed via confining OVs onto prototypical BiOCl surfaces of different structures. The critical understanding of OVs chemistry can help consolidate and advance the fundamental theories of photocatalysis, and also offer new perspectives and guidelines for the rational design of catalysts with satisfactory performance.
Nanoporous gold film (NPGF) electrode was fabricated by applying multicyclic potential scans on a polished gold electrode in an electrolyte composed of ZnCl 2 and benzyl alcohol. In the cathodic potential scan, Zn was first electrodeposited on the gold electrode surface, and Au-Zn alloy was then directly formed on the surface under an elevated temperature. In the subsequent anodic potential scan, dealloying of Zn took place, resulting in a nanostructured gold film. Furthermore, Zn was then electrodeposited onto the porous gold surface and a Au-Zn alloy was formed at the same time. Through controlling the parameters of cyclic voltammetry and cyclic times, we finally obtained a three-dimensional NPGF with nanopores. The resulting NPGF possessed ultrahigh roughness factor and surface area. Results showed that the electrochemical activity of the NPGF electrode was much higher than that of the polished gold electrode. We believe that the resulting NPGF electrode is promising in the fields of catalysis, sensors, and so on. Meanwhile, this multicyclic electrochemical alloying/dealloying method may be applied to fabricate other nanoporous metal films.
Interfacial polarization is reported as a brand new, efficient, and generalizable strategy to accelerate electrocatalytic reduction of N 2 to ammonia. The polarization is established by using an electric field to polarize N 2 . The electric field is triggered by protrusion-like single atoms anchored on MoS 2 . The interfacial polarization accelerates electron transfer from single atoms to N 2 and thus promotes N 2 reduction. As a result, ammonia synthesis in an electrochemical flow cell proceeds at a high rate of 36.1 G 3.6 mmol g À1 h À1 .
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.