Prior research has shown a tendency for environmental problems to be rated as more severe at the global level than at the local level. The present article reports reanalyses of a large cross-cultural data set (Study 1: k = 22, N = 3,277) and new cross-cultural data (Study 2: k = 8, N = 1,131) examining the prevalence of this spatial bias in the rated severity of environmental problems Article 268 Environment and Behavior 46(3)along with analyses of individual and country-level predictors of this bias. Results from multilevel modeling analyses showed that spatial bias was greater for happier and younger individuals and for those from smaller communities. We interpret these results as evidence for self-serving and "place-serving" biases in which the bias tempers the severity of environmental problems in one's local area. Considering the large cross-cultural evidence, we argue that spatial bias is a plausible candidate of a psychological universal identified by research in environmental psychology.

Crystalline organic compounds, 2-amino-6-methylpyrimidin-4-yl benzenesulfonate (AMPBS) and 2,6-diaminopyrimidin-4-yl benzenesulfonate (DAPBS), were prepared via O-benzenesulfonylation of 2-amino-6-methylpyrimidin-4-ol 1 and 2,6-diaminopyrimidin-4-ol 2, respectively. The structural interpretations were achieved unambiguously by single-crystal X-ray diffraction (SC-XRD) analysis. The Hirshfeld surface study showed that C−Hhydrogen bond interactions are the key contributors to the intermolecular stabilization in the crystal. Density functional theory (DFT) studies were used to obtain a better understanding of natural bond orbitals (NBOs) and nonlinear optical (NLO) analysis for AMPBS and DAPBS at the B3LYP/6-311G(d,p) level. The time-dependent density functional theory (TD-DFT)/CAM-B3LYP/6-311G(d,p) level was employed for frontier molecular orbital analysis of both compounds. DFT-based vibrations for C− H, CN, N−H, and stretching for C−C were found to be in good agreement with the experimental data. Overall, the theoretical findings were acquired in correspondence to the SC-XRD-based parameters. Intracharge transfer occurred in AMPBS and DAPBS compounds, which was evaluated through FMO activity. Global reactivity indices had been acquired utilizing energies of HOMO−LUMO orbitals. Overall, the theoretical findings related to AMPBS and DAPBS consist of promising correspondence to experimental findings. The theoretical-based study also exhibited that both AMPBS and DAPBS compounds contain promising NLO features.

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