Stable water-suspendable Cu+-doped ZnS nanocrystals (NCs) have been synthesized with mercaptopropionic acid (MPA) as a capping molecule. The nanocrystals have been characterized using a combination of experimental techniques including UV-vis and photoluminescence (PL) spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), inductively coupled plasma (ICP), and extended X-ray absorption fine structure (EXAFS). The UV-vis electronic absorption spectrum shows an excitonic peak at 310 nm, characteristic of quantum-confined ZnS NCs. This excitonic peak does not change noticeably with Cu+ doping. XRD confirms the formation of ZnS nanocrystals, and the average size of the NCs has been determined to be around 6 nm by TEM. The incorporation of Cu+ into the ZnS is manifested as a substantial red-shift of the emission band in the PL spectra upon addition of Cu2+ that was reduced into Cu+ during the synthesis reaction. EXAFS data were obtained to confirm copper doping as well as determine the local structure about Cu+ and Zn2+ in the NCs. Fitting to the EXAFS data for Cu+ suggests that most Cu+ ions are located near the surface within the ZnS NCs and that a significant fraction may be in the form of CuS as found in bulk material. These combined optical and structural studies have provided important new insight into the relevant electronic energy levels and their correlation to the optical and structural properties of ZnS:Cu,Cl NCs. This has important implications in potential applications of this phosphor material for solid state lighting, imaging, and other photonic devices.

An efficient method for the synthesis of heterogeneous gold catalysts has been developed. These catalysts were easily assembled from readily available silica materials and gold complexes. The heterogeneous catalysts exhibited superior reactivity in various reactions where protodeauration is the rate-limiting step. Dramatic enhancement in regio- and enantioselectivity was observed when compared to the homogeneous unsupported gold catalyst. The catalysts are easily recovered and recycled up to 11 times without loss of enantioselectivity.

Reported is the design and modular synthesis of a dual metal–dual semiconductor heterostructure with control over the dimensions and placement of its individual components. Analogous to molecular synthesis, colloidal synthesis is now evolving into a series of sequential synthetic procedures with separately optimized steps. We detail the challenges and parameters that must be considered when assembling such a multicomponent nanoparticle, and their solutions. This multicomponent nanosystem, Ru‐CdSe@CdS‐Pt, was designed to achieve charge carrier separation and directional transfer across different interfaces toward two separate redox catalysts. This heterostructure may potentially serve as a nanometric closed circuit photoelectrochemical cell.