Sulfides entering subduction zones can play an important role in the release of sulfur and metals to the mantle wedge and contribute to the formation of volcanic arc-associated ores. Fractionation of stable sulfur isotopes recorded by sulfides during metamorphism can provide evidence of fluid-rock interactions during metamorphism and give insights on sulfur mobilization. A detailed microtextural and geochemical study was performed on mineralized samples from two ocean floor-related sulfide deposits (Servette and Beth-Ghinivert) in high-pressure units of the Italian Western Alps, which underwent different metamorphic evolutions. The combination of microtextural investigations with d 34 S values from in situ ion probe analyses within individual pyrite and chalcopyrite grains allowed evaluation of the effectiveness of metamorphism in modifying the isotopic record and mobilizing sulfur and metals and have insights on fluid circulation within the slab. Textures and isotopic compositions inherited from the protolith are recorded at Beth-Ghinivert, where limited metamorphic recrystallization is attributed to limited interaction with metamorphic fluids. Isotopic modification by metamorphic processes occurred only at the submillimeter scale at Servette, where local interactions with infiltrating hydrothermal fluid are recorded by metamorphic grains. Notwithstanding the differences recorded by the two deposits, neither underwent intensive isotopic reequilibration or records evidence of intense fluid-rock interaction and S mobilization during metamorphism. Therefore, subducted sulfide deposits dominated by pyrite and chalcopyrite are unlikely to release significant quantities of sulfur to the mantle wedge and to arc magmatism sources at metamorphic grades below the lower eclogite facies.

In order to promote geosite conservation in the project entitled 'PROactive management of GEOlogical heritage in the PIEMONTE Region', we propose a comprehensive study involving the Monviso Massif (MM) geothematic area, one of the most outstanding symbols of the Alps and particularly of the Cottian Alps. Specifically, at the MM, the inventory of a number of different geosites whose conservation and development require different geologic and some additional non-geological expertise is considered: (1) some of the best preserved ophiolites in the Alps and the associated Cu-Fe mineralizations; (2) the lithostructural units in the Germanasca Valley; (3) the first primary source of jade in the Alps at the MM and its importance in terms of Neolithic to Bronze Age-polished stone implements; (4) the world-famous minerals such as coesite and giant pyrope, as well as type localities for new minerals (including carlosturanite); (5) the area, now buried under a debris flow, where Hannibal is thought to have regrouped his army while crossing the Alps; and (6) the biodiversity of lichens, microfungi and cyanobacteria colonizing the ophiolites, which can give additional value for the environmental assessment and evaluation of the MM outcrops. Following geodiversity identification, further stages will be devoted to develop appropriate plans for geodiversity conservation in this area.

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