We investigated an edge transformation in cove-type graphene nanoribbons based on changing the balance of zig-zag and armchair chains.
Purpose The role of acid-volatile sulfide (AVS) as a factor affecting (or reflecting the environmental conditions influencing) the behavior of metals has been evidenced in anoxic sediments. However, sediment quality studies tend not to consider any potential AVS role when sum of simultaneously extracted metal (ΣSEM) concentrations exceed AVS concentrations, restricting the application of the AVS model to predict toxicity, rather than coupling this model (when applicable) with other possible interpretations of metal-AVS relations. Materials and methods The relations between total organic carbon (TOC), AVS, and simultaneously extracted Fe, Cd, Cu, Ni, Pb, and Zn were investigated in sediment cores from two eutrophicated estuaries in Guanabara Bay (SE Brazil) in order to contribute to our understanding about metal-AVS relations in conditions of variable ΣSEM and AVS levels, due to gradients of eutrophication and metal contamination. Results and discussion Correlation analyses indicated a more important role of TOC, AVS, and Fe in the mechanisms affecting trace metal distribution in the less eutrophicated estuary. This suggests that AVS was a more important binding phase, or at least a better proxy for biogeochemical conditions affecting metal distribution, when it exceeds the sum of simultaneously extracted Cd, Cu, Ni, Pb, and Zn concentrations (ΣSEM). However, this potential role of AVS in anoxic estuarine sediments should not be discarded before evaluating individual metals-AVS relations even when ΣSEM levels exceed AVS levels, since the biogeochemical controls on the behavior of individual metals may be also related to metal-AVS associations in this situation (as indicated for Cu and Ni in the more eutrophicated estuary). The same is suggested for all AVS-based approaches, such as the (ΣSEM−AVS)/f OC (organic carbon normalization of excess ΣSEM), since (ΣSEM−AVS)/f OC values were mostly positive and significantly higher in the more eutrophicated estuary.Conclusions Although the importance of metal relations to AVS in evaluating individual metal behavior in anoxic estuarine sediments may not be restricted to situations in which AVS levels exceed ΣSEM levels (as observed for Ni and Cu in the present study), metal-AVS relations were apparently favored in this situation. Approaches in this way are recommended for future research, coupling the possibilities of metal behavior interpretations (and often predictions) allowed by AVS models.
A sediment core from Guanabara Bay (Brazil) was analyzed for 210 Pb dating, grain size, total organic carbon (TOC) and total nitrogen, carbon stable isotope ratio (d 13 C), nitrogen stable isotope ratio (d 15 N) and the metals Fe, Mn, Ni, Co, Cu, Pb, V and Zn, to assess the influence of land use changes on the aquatic system in a region for which large industrial and urban development is expected in the next few decades. To obtain baseline data for improving the monitoring of the expected increase in anthropogenic impacts from surrounding drainage basins, a multivariate analysis of data from different sediment layers was carried out to evaluate the dated sediment record. The geochemical data suggested three different sedimentary phases along the last 200 years. Before the 1880s, the highest clay and TOC contents were observed, where the C/N ratios and the d 13 C values suggested a mixture of algal and terrestrial organic matter and the lowest concentrations of Co, Cu, Pb, V and Zn, for which background levels were estimated (4.6, 2.7, 14.9, 24.3 and 70.2 mg kg -1 , respectively). From the 1880s to the 1950s, the metal concentrations and sand particles increased, but no change in organic matter quality was observed, reflecting a period of land use change, still without significant sewage input. After the 1950s, the sedimentation rate increased from 0.42 to 0.77 cm year -1 and increasing urban sewage input was evidenced by lower C/N ratios, higher d 15 N, decrease of Fe and Mn concentrations and increased fluxes of metals and TOC, which showed a good relationship with population growth data.
When an arbitrarily-shaped body is fully immersed in a liquid in equilibrium, it gets from the liquid a non-null hydrostatic force known as buoyant force. It is an easy task to apply the divergence theorem to show that this force agrees to that predicted by the well-known Archimedes' principle, namely an upward force whose magnitude equals the weight of the displaced liquid. Whenever this topic is treated in physics and engineering textbooks, a uniform gravitational field is assumed, which is a good approximation near the surface of the Earth. Would this approximation be essential for that law to be valid? In this note, starting from a surface integral of the pressure forces exerted by the fluid, we obtain a volume integral for the buoyant force valid for nonuniform gravitational fields. By comparing this force to the weight of the displaced fluid we show that the above question admits a negative answer as long as these forces are measured in the same place. The subtle possibility, missed in literature, of these forces to be distinct when measured in different places is pointed out.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.