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The CIDA (Cometary and Interstellar Dust Analyzer) instrument on the Stardust spacecraft is a time-of-flight mass spectrometer used to analyze ions formed when fast dust particles strike the instrument's target. In the spectra of 45 presumably interstellar particles, quinone derivates were identified as constituents in the organic component. The 29 spectra obtained during the flyby of Comet 81P/Wild 2 confirm the predominance of organic matter. In moving from interstellar to cometary dust, the organic material seems to lose most of its hydrogen and oxygen as water and carbon monoxide. These are now present in the comet as gas phases, whereas the dust is rich in nitrogen-containing species. No traces of amino acids were found. We detected sulfur ions in one spectrum, which suggests that sulfur species are important in cometary organics.

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During encounters with comet Halley, the experiment PICCA onboard GIOTTO measured the gas phase organic ion composition of the coma and the experiment PUMA onboard VEGA-1 measured the dust composition. Joining both results, we obtain a consistent picture of the parent organic matter from which dust and gas is produced. One recognizes a complex unsaturated polycondensate, which splits during coma-formation into the more refractory C=C,C-N-containing dust part, and the more volatile C=C,C-O-containing gas part. The responsible exothermal chemical reactions, which are triggered by the sunlight, may play a major role in the dynamics of coma formation.

The Cometary and Interstellar Dust Analyzer (CIDA) instrument analyzes the composition of individual grains in the cometary coma. As each particle impacts a silver plate, the high-impact energy due to the relative velocity of the spacecraft as it flies through the coma causes the elements and molecular compounds in the particle to become ionized. Using a fast time-of-flight mass spectrometer, a complete set of ions are detected for each impact, from a mass range of 1 (atomic hydrogen) up to a few thousand atomic mass units, encompassing all elements in the periodic table and many molecules, such as organic compounds. This experimental technique has already been applied with excellent success at Halley's comet, and the CIDA derivative instrument is flying on the Stardust mission, which will encounter comet Wild 2 in January of 2004. The data returned will give clues to the elemental and chemical composition of the dust component of this comet

Unisized 1.6-microm polystyrene microspheres coated with PEDOT (polyethylene-dioxythiophene) were accelerated to speeds of 6-16 km/s and shot onto a silver target. Either positive or negative ions, both instantaneously formed by the impact process, have been analyzed by time-of-flight mass spectrometry (TOF). Apparently, the processes that control the formation of ions of either polarity depend on the impact velocity. Comparing the results with those of secondary ion mass spectrometry with primary ion energy in both the elastic and the inelastic ((252)Cf-MS) energy loss regimes, some reaction mechanisms of the polymer ions for different energy densities could be elucidated. Some aspects of ion formation are also related to those found in pulsed laser ion generation from these microspheres. This investigation was performed in order to further improve the method of analyzing the organic fraction of interstellar, interplanetary, and cometary dust particles impinging on the targets of the "CIDA" time-of-flight (TOF) mass spectrometers on-board the NASA comet missions "STARDUST" and "CONTOUR".