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The temperature dependence of the energy gap of zinc-blende CdSe and Cd1−xZnxSe has been determined over the entire range of composition from optical transmission and reflection measurements at temperatures between 5 and 300 K. The experimental results can be expressed by the following modified empirical Varshni formula, whose parameters are functions of the composition x: Eg(x,T)=Eg(x,0)−β(x)T2/[T+γ(x)]. Eg(x,0) exhibits a nonlinear dependence on composition, according to Eg=Eg(0,0)(1−x)+Eg(1,0)x−ax(1−x). The parameters β(x) and γ(x) can be expressed by β(x)=β(0)(1−x)+β(1)x+bx(1−x) and γ(x)=γ(0)(1−x)+γ(1)x.

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It has been demonstrated that two closely spaced peaks in the infrared absorption spectra of several HgTe/ Hg 1−x Cd x Te͑112͒B superlattices ͑SL's͒ are due to the H1-E1 intersubband transition at the center of the Brillouin zone and the zone boundary. The miniband width agrees well with ͑8 ϫ 8 k · p͒ calculations. The intersubband transition energies of SL's with both large and small miniband widths have been compared with photoluminescence ͑PL͒ spectra over a temperature range of 5 -300 K for a number of superlattices with band gaps between 100 and 510 meV at 5 K. The band gap as determined from the peak of the first derivative of the absorption coefficient, i.e., the corresponding intersubband transition energy, agrees well with the PL peak energy. With increasing temperature the PL peak energy increases faster than the band gap by a range of factors given by 0.25-0.75k B T, however, which are well within the width of the thermally broadened PL peaks.