We present the phase diagram of free charges (electrons and holes), excitons, and biexcitons in highly excited CdSe nanoplatelets that predicts a crossover to a biexciton-dominated region at easily attainable low temperatures or high photoexcitation densities. Our findings extend previous work describing only free charges and excitons by introducing biexcitons into the equation of state, while keeping the exciton and biexciton binding energies constant in view of the relatively low density of free charges in this material. Our predictions are experimentally testable in the near future and offer the prospect of creating a quantum degenerate, and possibly even superfluid, biexciton gas. Furthermore, we also provide simple expressions giving analytical insight into the regimes of photoexcitation densities and temperatures in which excitons and biexcitons dominate the response of the nanoplatelets.
We show that the finite lateral sizes of ultrathin CdSe nanoplatelets strongly affect both their photoluminescence and optical absorption spectra. This is in contrast to the situation in quantum wells, in which the large lateral sizes may be assumed to be infinite. The lateral sizes of the nanoplatelets are varied over a range of a few to tens of nanometers. For these sizes excitons experience in-plane quantum confinement, and their center-of-mass motion becomes quantized. Our direct experimental observation of the discretization of the exciton center-of-mass states can be well understood on the basis of the simple particle-in-a-box model.
We present the phase diagram of free charges (electrons and holes), excitons, and biexcitons in highly excited CdSe nanoplatelets that predicts a crossover to a biexciton-dominated region at easily attainable low temperatures or high photoexcitation densities. Our findings extend previous work describing only free charges and excitons by introducing biexcitons into the equation of state, while keeping the exciton and biexciton binding energies constant in view of the relatively low density of free charges in this material. Our predictions are experimentally testable in the near future and offer the prospect of creating a quantum degenerate, and possibly even superfluid, biexciton gas. Furthermore, we also provide simple expressions giving analytical insight into the regimes of photoexcitation densities and temperatures in which excitons and biexcitons dominate the response of the nanoplatelets.
We provide a framework to compute the dynamics of massive Dirac fermions using holography. To this end we consider two bulk Dirac fermions that are coupled via a Yukawa interaction and propagate on a gravitational background in which a mass deformation is introduced. Moreover, we discuss the incorporation of this approach in semiholography. The resulting undoped fermionic spectral functions indeed show that the Yukawa coupling induces a gap in the holographic spectrum, whereas the semiholographic extension is in general gapped but additionally contains a quantum critical point at which the effective fermion mass vanishes and a topological phase transition occurs. Furthermore, when introducing doping, the fermionic spectral functions show a quantum phase transition between a gapped material and a Fermi liquid.
We examine the impact of quantum confinement on the interaction potential between two charges in twodimensional semiconductor nanosheets in solution. The resulting effective potential depends on two length scales, namely, the thickness d and an emergent length scale d * ≡ d/ sol , where is the permittivity of the nanosheet and sol is the permittivity of the solvent. In particular, quantum confinement, and not electrostatics, is responsible for the logarithmic behavior of the effective potential for separations smaller than d, instead of the one-over-distance bulk Coulomb interaction. Finally, we corroborate that the exciton binding energy also depends on the two-dimensional Bohr radius a 0 in addition to the length scales d and d * and analyze the consequences of this dependence.
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