A series of six N-benzoyl-thiocarbamic-0constants of which have been determined in 75 vol% dioxalkylesters (R=Me, Et, i-Pr, Benzyl, n-Hex, n-Dodec; 1ane/water. The molecular structure of bis(0-ethyl-N-benzoyl-6 ) has been prepared and characterized. They are weak thiocarbamato)nickel(II) 2a is presented. The coordination of monoprotic acids. The compounds behave as fairly stable the nickel atom is square planar with the two sulphur atoms and versatile bidentate (0,s)-chelating ligands towards mul-in cis position. tivalent metal ions e. g. Ni(II), Cu(II), Pb(I1) the stability
Silber(I) bildet mit N,N‐Diethyl‐N′‐benzoyl‐thioharnstoff HL in Dioxan/Wasser‐Mischung, abhängig vom pH‐Wert, dem molaren Verhältnis der Reaktanden und ihren Konzentrationen, kationische, neutrale und anionische Komplexe, in denen der Ligand in unterschiedlicher Weise koordiniert. Für diese Komplexe wurden pAg‐ und pH‐potentiometrisch Stabilitätskonstanten bestimmt. Repräsentative Komplexe konnten in festem Zustand isoliert werden, darunter ein cyclischer Komplex [AgL]4, dessen Struktur durch Röntgenbeugung bestimmt wurde.
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