In contrast to monovalent lithium or sodium ions, the reversible insertion of multivalent ions such as Mg and Al into electrode materials remains an elusive goal. Here, we demonstrate a new strategy to achieve reversible Mg and Al insertion in anatase TiO, achieved through aliovalent doping, to introduce a large number of titanium vacancies that act as intercalation sites. We present a broad range of experimental and theoretical characterizations that show a preferential insertion of multivalent ions into titanium vacancies, allowing a much greater capacity to be obtained compared to pure TiO. This result highlights the possibility to use the chemistry of defects to unlock the electrochemical activity of known materials, providing a new strategy for the chemical design of materials for practical multivalent batteries.
In this work, the electrogeneration of peroxodisulfate from a 1 M H 2 SO 4 solution on boron-doped diamond microelectrodes array has been studied. The peroxodisulfate is detected at the vicinity of the boron doped diamond electrode, with the SECM probe, only when the polarization of the microarray is greater than 2.
The packing of large-diameter columns for liquid chromatography is still difficult and numerous publications have reported results from tests which prove the packing is heterogeneous. The slurry is more compact in the wall region and this reduces the flow of the mobile phase, leading to distortion of the sample zone in the column and generation of peak tailing. A new type of injection system for the head of the column has been developed which divides the flow of the solvent from the pump into two parts. One, without sample, is directed to a crown injector, close to the wall. By adjusting the ratio of this flow to that of the bulk flow it is possible to increase the speed of the mobile phase in this part of the stationary phase and reduce distortion of the sample zone. The other part of the solvent carries the sample to the stationary phase through a distributor. The results demonstrate the benefits of this annular injection system, which include increased efficiency and improved column stability.
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